Diethyl 4-bromoisophthalate

Base Information

Chemical Name:Diethyl 4-bromoisophthalate
CAS No.:56984-35-1
Molecular Formula:C12H13BrO4
Molecular Weight:301.137
Hs Code.:
DSSTox Substance ID:DTXSID90468039
Nikkaji Number:J1.153.480E
Wikidata:Q82295137

Synonyms:DIETHYL 4-BROMOISOPHTHALATE;56984-35-1;4-bromoisophthalic acid diethyl ester;SCHEMBL277473;DTXSID90468039;AMIIIXXHQPWVFM-UHFFFAOYSA-N;AB69254;FT-0709685;4-bromo-1,3-benzenedicarboxylic acid diethyl ester

Suppliers and Price of Diethyl 4-bromoisophthalate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Diethyl 4-bromoisophthalate

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:299.99972
Heavy Atom Count:17
Complexity:280

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CC(=C(C=C1)Br)C(=O)OCC

Technology Process of Diethyl 4-bromoisophthalate

There total 4 articles about Diethyl 4-bromoisophthalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 64-17-5
ethanol

: 6939-93-1
4-bromo-isophthalic acid

: 56984-35-1
diethyl 4-bromobenzene-1,3-dicarboxylate

Guidance literature:: With sulfuric acid; for 12h; Heating;
DOI:10.1248/cpb.47.1073

Reference yield:

: 583-70-0
1-bromo-2,4-dimethylbenzene

: 56984-35-1
diethyl 4-bromobenzene-1,3-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium permanganate / water / 16 h / Reflux; Inert atmosphere

2: sulfuric acid / 16 h / 78 °C / Inert atmosphere

With potassium permanganate; sulfuric acid; In water;
DOI:10.1021/jo201013q

Reference yield:

: 2840-29-1
3-amino-4-bromobenzoic acid

: 56984-35-1
diethyl 4-bromobenzene-1,3-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium nitrite; hydrochloric acid / Diazotization

2: hydrochloric acid

3: hydrogen chloride

With hydrogenchloride; sodium nitrite;