Benzeneacetyl chloride, a-(phenylmethylene)-

Base Information

Chemical Name:Benzeneacetyl chloride, a-(phenylmethylene)-
CAS No.:58085-33-9
Molecular Formula:C15H11ClO
Molecular Weight:242.705
Hs Code.:

Synonyms:2,3t-Diphenyl-acryloylchlorid;seq.-trans-2,3-Diphenyl-acryloylchlorid;2,3t-Diphenyl-acrylsaeure-chlorid;α-phenylcinnamoyl chloride;2,3t-diphenyl-acrylic acid-chloride;α-Phenyl-trans-zimtsaeurechlorid;

Suppliers and Price of Benzeneacetyl chloride, a-(phenylmethylene)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzeneacetyl chloride, a-(phenylmethylene)-

Chemical Property:

Melting Point:172 °C
Boiling Point:355.0±21.0 °C(Predicted)
PSA：17.07000
Density:1?+-.0.06 g/cm3(Predicted)
LogP:3.99260

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzeneacetyl chloride, a-(phenylmethylene)-

There total 11 articles about Benzeneacetyl chloride, a-(phenylmethylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 91-48-5
(E)-2,3-diphenylpropenoic acid

: 58085-33-9,60135-02-6,51388-67-1
α-phenylcinnamoyl chloride

Guidance literature:: With oxalyl dichloride; N,N-dimethyl-formamide; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2009.08.047

Reference yield: 97.0%

: 91-47-4,91-48-5,3368-16-9
2,3-diphenylacrylic acid

: 58085-33-9
α-phenyl-cinnamoyl chloride

Guidance literature:: With phosgene; In water; at 20 ℃; for 4h;
DOI:10.1016/j.ejmech.2019.02.074

Reference yield:

: 15206-55-0
methyl 2-oxo-2-phenylacetate

: 58085-33-9
α-phenyl-cinnamoyl chloride

Guidance literature:: Multi-step reaction with 3 steps

1: Hexamethylphosphorous triamide / acetonitrile; water / 3.5 h / -40 - 60 °C

2: lithium hydroxide monohydrate / water; 1,4-dioxane / Reflux

3: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 20 °C

With oxalyl dichloride; lithium hydroxide monohydrate; N,N-dimethyl-formamide; Hexamethylphosphorous triamide; In 1,4-dioxane; dichloromethane; water; acetonitrile;
DOI:10.1021/acs.orglett.0c00620