2-(BroMoMethyl)-6-fluoronaphthalene

Base Information

Chemical Name:2-(BroMoMethyl)-6-fluoronaphthalene
CAS No.:581-72-6
Molecular Formula:C11H8BrF
Molecular Weight:239.08400
Hs Code.:
Mol file:581-72-6.mol

Synonyms:2-Fluoro-6-bromomethylnaphthalen;6-fluoronaphth-2-ylmethyl bromide;2-Bromomethyl-6-fluoro-naphthalene;2-Brommethyl-6-fluor-naphthalin;2-Bromomethyl-6-fluoronaphthalene;2-(bromomethyl)-6-fluoronaphthalene;

Suppliers and Price of 2-(BroMoMethyl)-6-fluoronaphthalene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alichem
2-(Bromomethyl)-6-fluoronaphthalene
1g
$ 1752.40

Alichem
2-(Bromomethyl)-6-fluoronaphthalene
500mg
$ 931.00

Total 5 raw suppliers

Chemical Property of 2-(BroMoMethyl)-6-fluoronaphthalene

Chemical Property:

Melting Point:52 - 52.5 °C
Boiling Point:125-130 °C(Press: 2 Torr)
PSA：0.00000
Density:1.520±0.06 g/cm3(Predicted)
LogP:3.87380

Purity/Quality:

99% ^*data from raw suppliers

2-(Bromomethyl)-6-fluoronaphthalene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(BroMoMethyl)-6-fluoronaphthalene

There total 9 articles about 2-(BroMoMethyl)-6-fluoronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 944351-48-8
(6-fluoronaphthalen-2-yl)methanol

: 581-72-6
2-bromomethyl-6-fluoronaphthalene

Guidance literature:: (6-fluoronaphthalen-2-yl)methanol; With phosphorus tribromide; In dichloromethane; at 20 ℃; for 3h;

With ammonium chloride; In dichloromethane;

Reference yield:

: 324-42-5
2-fluoro-6-methylnaphthalene

: 581-72-6
2-bromomethyl-6-fluoronaphthalene

Guidance literature:: With bromine; at 210 ℃; Irradiation;
DOI:10.1021/ja01189a002

Reference yield:

: 29419-14-5
6-fluoro-2-tetralone

: 581-72-6
2-bromomethyl-6-fluoronaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: TiCl₄ / CH₂Cl₂; tetrahydrofuran / 2 h / 0 °C

2: Ph₃COH, TFA / 48 h / Ambient temperature

3: N-bromosuccinimide, AIBN / CCl₄ / 0.5 h / Heating

With N-Bromosuccinimide; triphenylmethyl alcohol; 2,2'-azobis(isobutyronitrile); titanium tetrachloride; trifluoroacetic acid; In tetrahydrofuran; tetrachloromethane; dichloromethane;
DOI:10.1021/jm00069a006