Carbonic acid, 2-cyclohexen-1-yl methyl ester

Base Information

• Chemical Name: Carbonic acid, 2-cyclohexen-1-yl methyl ester
• CAS No.: 58329-99-0
• Molecular Formula: C8H12O3
• Molecular Weight: 156.181
• Mol file: 58329-99-0.mol

Synonyms:methyl cyclohex-2-enyl carbonate;methyl cyclohex-2-en-1-yl carbonate;cyclohex-2-en-1-yl methyl carbonate;cyclohex-2-enyl methyl carbonate;(+/-)-cyclohex-2-enyl methyl carbonate;methyl (+/-)-(cyclohex-2-enyl) carbonate;

Chemical Property of Carbonic acid, 2-cyclohexen-1-yl methyl ester

Chemical Property:

• Boiling Point: 240.6±20.0 °C(Predicted)
• PSA: 35.53000
• Density: 1.06±0.1 g/cm3(Predicted)
• LogP: 1.87810

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonic acid, 2-cyclohexen-1-yl methyl ester

There total 4 articles about Carbonic acid, 2-cyclohexen-1-yl methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Cyclohex-2-enol (822-67-3) + carbonic acid dimethyl ester (616-38-6) → cyclohex-2-enyl methyl carbonate (58329-99-0)

Guidance literature:

carbonic acid dimethyl ester; With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate; at 20 ℃;

Cyclohex-2-enol; for 1h; Molecular sieve; Reflux;

DOI:10.1039/c2cc34987f

Reference yield: 98.0%

Cyclohex-2-enol (822-67-3) + methyl chloroformate (79-22-1) → cyclohex-2-enyl methyl carbonate (58329-99-0)

Guidance literature:

With pyridine; In dichloromethane; at 0 ℃; for 11h;

DOI:10.1021/ja067003h

Reference yield:

sodium methylate (124-41-4) + cyclohexene (110-83-8) → cyclohex-2-enyl methyl carbonate (58329-99-0)

Guidance literature:

In methanol; (electrolysis);

upstream raw materials:

sodium methylate

cyclohexene

Cyclohex-2-enol

methyl chloroformate

Downstream raw materials:

Trimethylmethoxysilane

cyclohex-2-enecarbonitrile

(S)-(cyclohex-2-en-1-ylsulfonyl)benzene

dimethyl 2-(cyclohex-2-en-1-yl)malonate