Tris(2,4,6-trimethylphenyl)alumane

Base Information

• Chemical Name: Tris(2,4,6-trimethylphenyl)alumane
• CAS No.: 58336-22-4
• Molecular Formula: C27H33Al
• Molecular Weight: 384.541
• DSSTox Substance ID: DTXSID50587235

Synonyms:Trimesitylaluminum;Tris(2,4,6-trimethylphenyl)alumane;58336-22-4;Aluminum, tris(2,4,6-trimethylphenyl)-;DTXSID50587235;VFNHUKAYAKVJSR-UHFFFAOYSA-N;tris(2,4,6-trimethylphenyl)aluminium

Chemical Property of Tris(2,4,6-trimethylphenyl)alumane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 384.2397645
• Heavy Atom Count: 28
• Complexity: 393

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Al](C2=C(C=C(C=C2C)C)C)C3=C(C=C(C=C3C)C)C)C

Technology Process of Tris(2,4,6-trimethylphenyl)alumane

There total 3 articles about Tris(2,4,6-trimethylphenyl)alumane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

aluminum (III) chloride (7446-70-0,7784-13-6) + mesityllithium (5806-59-7) → trimesitylaluminium (58336-22-4)

Guidance literature:

In toluene; for 4h; Inert atmosphere; Reflux;

DOI:10.1039/d0dt02498h

Reference yield:

aluminum (III) chloride (7446-70-0,7784-13-6) + 2-mesitylmagnesium bromide (2633-66-1) → trimesitylaluminium (58336-22-4)

Guidance literature:

In tetrahydrofuran; at -70 - 20 ℃; for 16h; Glovebox; Schlenk technique;

DOI:10.1021/acs.inorgchem.8b01009

Reference yield:

trimesitylaluminium*1.2THF → trimesitylaluminium (58336-22-4)

Guidance literature:

byproducts: THF; 180-200°C; recrystn. (toluene), elem. anal.;

upstream raw materials:

aluminum (III) chloride

2-mesitylmagnesium bromide

mesityllithium

Downstream raw materials:

[((CH₃)3C₆H₂)2Al(Cl)]2

[((CH₃)3C₆H₂)2Al(SCH₂C₆H₅)]2

[((CH₃)3C₆H₂)2Al(SC₆H₅)]2

[Mes2Al(μ-SePh)]2

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