o-Hydroxyphenyl carbamate

Base Information

• Chemical Name: o-Hydroxyphenyl carbamate
• CAS No.: 35580-87-1
• Molecular Formula: C7H7 N O3
• Molecular Weight: 153.137
• Hs Code.: 2924299090
• European Community (EC) Number: 252-630-2
• UNII: L94PPV78J5
• DSSTox Substance ID: DTXSID50189051
• Nikkaji Number: J260.655K
• Wikidata: Q83060959
• Mol file: 35580-87-1.mol

Synonyms:o-Hydroxyphenyl carbamate;35580-87-1;2-hydroxyphenyl carbamate;EINECS 252-630-2;L94PPV78J5;UNII-L94PPV78J5;1,2-Benzenediol 1-carbamate;Phenolcarbamat;SCHEMBL140239;DTXSID50189051;AKOS006328345;1,2-BENZENEDIOL, 1-CARBAMATE

Chemical Property of o-Hydroxyphenyl carbamate

Chemical Property:

• Vapor Pressure: 5.59E-05mmHg at 25°C
• Boiling Point: 336.8°Cat760mmHg
• Flash Point: 157.5°C
• PSA: 73.54000
• Density: 1.359g/cm³
• LogP: 1.36350
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 153.042593085
• Heavy Atom Count: 11
• Complexity: 149

Purity/Quality:

98%Min ^*data from raw suppliers

ORTHO-HYDROXYPHENYL CARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)O)OC(=O)N

Technology Process of o-Hydroxyphenyl carbamate

There total 2 articles about o-Hydroxyphenyl carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) + urea (57-13-6) → 2-hydroxyphenyl carbamate (35580-87-1)

Guidance literature:

With zinc monoglycerolate; In neat (no solvent); at 140 ℃; for 7h; under 30.003 Torr; Green chemistry;

DOI:10.1039/c5ra05032d

Reference yield:

1,3-benzodioxol-2-one (2171-74-6) → 2-hydroxyphenyl carbamate (35580-87-1)

Guidance literature:

With ammonia;

Reference yield:

2-hydroxyphenyl carbamate (35580-87-1) + benzylamine (100-46-9) → benzylurea (538-32-9)

Guidance literature:

In ethanol; Heating;

upstream raw materials:

1,3-benzodioxol-2-one

benzene-1,2-diol

urea

Downstream raw materials:

N'-cyclohexylurea

N-Ethylurea

1,1-Dimethyl-semicarbazid

1-butyl-urea