(2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one

Base Information

Chemical Name:(2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one
CAS No.:58648-14-9
Molecular Formula:C₁₁H₁₆O₂
Molecular Weight:180.247
Hs Code.:
DSSTox Substance ID:DTXSID10571438
Nikkaji Number:J841.316I
Wikidata:Q82459520

Synonyms:58648-14-9;(2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one;DTXSID10571438

Suppliers and Price of (2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one

Chemical Property:

XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:180.115029749
Heavy Atom Count:13
Complexity:243

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)C1(CCCCC1=O)CC=C
Isomeric SMILES:CC(=O)[C@@]1(CCCCC1=O)CC=C

Technology Process of (2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one

There total 3 articles about (2R)-2-Acetyl-2-(prop-2-en-1-yl)cyclohexan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 591-87-7
Allyl acetate

: 874-23-7,125117-37-5
2-acetylcyclohexanone

: 67679-08-7
(S)-2-acetyl-2-(2-propenyl)cyclohexanone

: 58648-14-9
(R)-2-acetyl-2-(2-propenyl)cyclohexanone

Guidance literature:: With di-μ-chlorobis(?-allyl)dipalladium + ferrocenylphosphine; sodium hydride; In tetrahydrofuran; at -60 ℃; Mechanism; other palladium catalysts; other temps. and reaction times; other allyl compounds, and other β-diketones; steroselectivity of reactions;
DOI:10.1021/jo00236a023

Reference yield:

: 3066-75-9
allyl diethyl phosphate

: 874-23-7,125117-37-5
2-acetylcyclohexanone

: 67679-08-7
(S)-2-acetyl-2-(2-propenyl)cyclohexanone

: 58648-14-9
(R)-2-acetyl-2-(2-propenyl)cyclohexanone

Guidance literature:: With di-μ-chlorobis(?-allyl)dipalladium + ferrocenylphosphine; sodium hydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, 0 deg C, 30 min, 2.) THF, -50 deg C, 40 h;
DOI:10.1021/jo00236a023

Reference yield:

: 35466-83-2
allyl methyl carbonate

: 874-23-7,125117-37-5
2-acetylcyclohexanone

: 67679-08-7
(S)-2-acetyl-2-(2-propenyl)cyclohexanone

: 58648-14-9
(R)-2-acetyl-2-(2-propenyl)cyclohexanone

Guidance literature:: With di-μ-chlorobis(?-allyl)dipalladium + ferrocenylphosphine; sodium hydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, 0 deg C, 30 min, 2.) THF, -50 deg C, 43 h;
DOI:10.1021/jo00236a023