3066-75-9

Basic information

• Product Name: DIETHYL ALLYL PHOSPHATE 98
• Synonyms: DIETHYL ALLYL PHOSPHATE 98;Diethyl Allyl Phosphate 98%;diethyl prop-2-enyl phosphate;phosphoric acid allyl diethyl ester;Allyl Diethyl Phosphate
• CAS NO: 3066-75-9
• Molecular Formula: C₇H₁₅O₄P
• Molecular Weight: 194.17
• Product Categories: Organic Building Blocks;Organic Phosphates/Phosphites;Phosphorus Compounds
• Mol File: 3066-75-9.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 45-46 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.09 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.169mmHg at 25°C
• Refractive Index: n20/D 1.422(lit.)
• CAS DataBase Reference: DIETHYL ALLYL PHOSPHATE 98(CAS DataBase Reference)
• NIST Chemistry Reference: DIETHYL ALLYL PHOSPHATE 98(3066-75-9)
• EPA Substance Registry System: DIETHYL ALLYL PHOSPHATE 98(3066-75-9)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 3066-75-9(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 3066-75-9 differently. You can refer to the following data:
1. Allyl Diethyl Phosphate is a flame-retardant agent for the modification of rubber wood with styrene.
2. DEAP may be used as a flame retardant additive in the preparation of rubber wood/polymer composite. It can also be used for the stereoselective synthesis of cis- or trans-3-vinyl-β-lactam compounds and also for the fabrication of amphoteric surfaces on silicone substrates.

General Description

Diethyl allyl phosphate can be prepared by reacting ethanol and POCl3.It can undergo free radical polymerization to form a flame retardant polymer, poly DEAP

InChI:InChI=1/C7H15O4P/c1-4-7-11-12(8,9-5-2)10-6-3/h4H,1,5-7H2,2-3H3

Upstream product

• 814-49-3 diethyl chlorophosphate 
• 107-18-6 allyl alcohol 
• 681035-21-2 (2-oxo-5,5-diphenyl-oxazolidin-3-yl)-phosphonic acid diethyl ester 
• 64-17-5 ethanol 
• 122-52-1 triethyl phosphite 
• 762-04-9 phosphonic acid diethyl ester 
• 2622-05-1 allylmagnesium bromide 
• 35335-22-9 Oxiranylidene-2,2-bis(phosphonic acid) tetraethyl ester 
• 598-02-7 Diethyl phosphate 
• 106-95-6 allyl bromide 

Downstream Products

• 94-66-6 2-allylcyclohexan-1-one 
• 36040-02-5 2,6-diallyl-1-cyclohexanone 
• 67679-08-7 (S)-2-acetyl-2-(2-propenyl)cyclohexanone 
• 58648-14-9 (R)-2-acetyl-2-(2-propenyl)cyclohexanone 
• 109387-97-5 cis-1-(4-Methoxyphenyl)-3-vinyl-4-benzoyl-2-azetidinone 
• 124156-22-5 cis-1-(4-Methoxyphenyl)-3-vinyl-4-(methoxycarbonyl)-2-azetidinone 
• 762-62-9 4,4-dimethylpent-1-ene 
• 40637-56-7 dimethyl allylmalonate 
• 16212-05-8 (allylsulfonyl)benzene 
• 1623-14-9 ethyl phosphate 
• 1123-34-8 1-allyl-1-cyclohexanol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 

Relevant articles and documents

New insights into the chemistry of gem-bis(phosphonates): Unexpected rearrangement of Michael-type acceptors

The use of tetraethyl ethylidenebis(phosphonate) as a Michael acceptor with different nucleophiles was investigated. It was found that in some cases this compound undergoes phosphate removal, depending on the nature of the nucleophile. The chemical behavior of its epoxy derivative tetraethyl oxiranylidenebis(phosphonate) as an electrophile was also studied. This compound underwent a very attractive and remarkable phosphonate-phosphate rearrangement resulting in the enol phosphate 8 regardless of the nucleophile employed. Different mechanistic studies were conducted in an attempt to explain the mechanisms involved. To the best of our knowledge, this reaction constitutes a remarkable novelty, being the first reported rearrangement reaction of an epoxy derivative of a gem-bis(phosphonate). In addition, evidence supporting the involvement of a radical or a polar mechanism, depending on the nature of the nucleophile, is discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.

Synthetic method of asymmetric phosphate compound

The invention relates to the field of lithium ion batteries, and discloses a synthetic method of an asymmetric phosphate compound. The method comprises the following steps: reacting phosphorus oxychloride represented by a formula (I), a compound represent

Tunable Redox Potential Photocatalyst: Aggregates of 2,3-Dicyanopyrazino Phenanthrene Derivatives for the Visible-Light-Induced α-Allylation of Amines

This work highlights the tunable redox potential of 6,11-dibromo-2,3-dicyanopyrazinophenanthrene (DCPP3) aggregates, which can be formed through physical π-πstacking interactions with other DCPP3 monomers. Electrochemical and scanning electron microscopy showed that the reduction potential of [DCPP3]n aggregates could be increased by decreasing their size. The size of [DCPP3]n aggregates could be regulated by controlling the concentration of DCPP3 in an organic solvent. As such, a fundamental understanding of this tunable redox potential is essential for developing new materials for photocatalytic applications. The [DCPP3]n aggregates as a visible-light photocatalyst in combination with Pd catalysts in the visible-light-induced α-allylation of amines were used. This [DCPP3]n photocatalyst exhibits excellent photo- and electrochemical properties, including a remarkable visible-light absorption, long excited-state lifetime (16.6 μs), good triplet quantum yield (0.538), and high reduction potential (Ered([DCPP3]n/[DCPP3]n-) > -1.8 V vs SCE).