Benzonitrile, 4-(trimethylstannyl)-

Base Information

Chemical Name:Benzonitrile, 4-(trimethylstannyl)-
CAS No.:58666-77-6
Molecular Formula:C10H13NSn
Molecular Weight:265.93
Hs Code.:
DSSTox Substance ID:DTXSID70457007

Synonyms:Benzonitrile, 4-(trimethylstannyl)-;58666-77-6;SCHEMBL5952305;DTXSID70457007

Suppliers and Price of Benzonitrile, 4-(trimethylstannyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 1 raw suppliers

Chemical Property of Benzonitrile, 4-(trimethylstannyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:267.007002
Heavy Atom Count:12
Complexity:188

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)(C)C1=CC=C(C=C1)C#N

Technology Process of Benzonitrile, 4-(trimethylstannyl)-

There total 15 articles about Benzonitrile, 4-(trimethylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1066-45-1
trimethyltin(IV)chloride

: 7440-23-5
sodium

: 17311-01-2
(4-cyanophenyl)trimethylammonium iodide

: 58666-77-6
(4-cyanophenyl)trimethylstannane

Guidance literature:: With methyl iodide; In ammonia; condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, then addn. of CNC6H4NMe3I; holding in dark for 0.08 h; quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether;
DOI:10.1021/om000859p

Reference yield: 98.0%

: 3058-39-7
4-iodobenzonitrile

: 661-69-8
hexamethyldistannane

: 58666-77-6
(4-cyanophenyl)trimethylstannane

Guidance literature:: dichloro bis(acetonitrile) palladium(II); In N,N-dimethyl-formamide; byproducts: (CH3)3SnI; Me6Sn2, p-CNC6H4I dissolved in DMF in a flask, catalyst added with stirring, reacted for 10 min at 20°C; water added, extracted with ether, extracts filtered, washed with water, dried with Na2SO4, chromy.(silica gel, hexane/ether 2:1);

Reference yield: 95.0%

: 3058-39-7
4-iodobenzonitrile

: 1066-45-1
trimethyltin(IV)chloride

: 58666-77-6
(4-cyanophenyl)trimethylstannane

Guidance literature:: 4-iodobenzonitrile; With isopropylmagnesium chloride; In tetrahydrofuran; diethyl ether; at -40 ℃; for 1h;

trimethyltin(IV)chloride; In tetrahydrofuran; diethyl ether; at -40 - 20 ℃;
DOI:10.1002/anie.201304443