Dimethyl (3-chlorobenzoyl)phosphonate

Base Information

Chemical Name:Dimethyl (3-chlorobenzoyl)phosphonate
CAS No.:58879-27-9
Molecular Formula:C9H10ClO4P
Molecular Weight:248.603
Hs Code.:
DSSTox Substance ID:DTXSID10505354
Wikidata:Q82360403

Synonyms:58879-27-9;Dimethyl (3-chlorobenzoyl)phosphonate;DTXSID10505354

Suppliers and Price of Dimethyl (3-chlorobenzoyl)phosphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Dimethyl (3-chlorobenzoyl)phosphonate

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:248.0005235
Heavy Atom Count:15
Complexity:273

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COP(=O)(C(=O)C1=CC(=CC=C1)Cl)OC

Technology Process of Dimethyl (3-chlorobenzoyl)phosphonate

There total 1 articles about Dimethyl (3-chlorobenzoyl)phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 618-46-2
m-Chlorobenzoyl chloride

: 121-45-9
phosphorous acid trimethyl ester

: 58879-27-9
1-Oxo-(3-chlorphenyl)methanphosphonsaeuredimethylester

Guidance literature:: DOI:10.1007/BF00909658

Reference yield: 90.0%

: 151-50-8
potassium cyanide

: 58879-27-9
1-Oxo-(3-chlorphenyl)methanphosphonsaeuredimethylester

: 623-49-4
ethyl cyanoformate

: (ethoxycarbonyl)(cyano)(3-chlorophenyl)methyl dimethyl phosphate

Guidance literature:: With 18-crown-6 ether; In tetrahydrofuran; at 20 ℃;
DOI:10.1021/jo0710073

Reference yield: 74.0%

: 59414-23-2
1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene

: 58879-27-9
1-Oxo-(3-chlorphenyl)methanphosphonsaeuredimethylester

: 1293917-93-7
dimethyl (2-(3-chlorophenyl)-4-oxo-3,4-dihydro-2H-pyran-2-yl)phosphonate

Guidance literature:: 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene; 1-Oxo-(3-chlorphenyl)methanphosphonsaeuredimethylester; In toluene; at 100 ℃; for 14h; Inert atmosphere;

With trifluoroacetic acid; In toluene; at 0 ℃;
DOI:10.1016/j.tet.2011.02.007