2-(2-phenylvinyl)-1,3-benzothiazole

Base Information

• Chemical Name: 2-(2-phenylvinyl)-1,3-benzothiazole
• CAS No.: 59066-61-4
• Molecular Formula: C15H11NS
• Molecular Weight: 237.325
• Mol file: 59066-61-4.mol

Synonyms:2-styryl-N-tosylbenzothiazole;(E)-2-(2-phenylvinyl)benzothiazole;(E)-2-(2-Phenylethenyl)benzothiazol;2-[(E)-2-phenylvinyl]benzothiazole;(E)-2-styrylbenzo[d]thiazole;2-(2-phenyl-E-ethenyl)benzothiazole;

Chemical Property of 2-(2-phenylvinyl)-1,3-benzothiazole

Chemical Property:

• PSA: 41.13000
• LogP: 4.46670

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(2-phenylvinyl)-1,3-benzothiazole

There total 68 articles about 2-(2-phenylvinyl)-1,3-benzothiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-Methylbenzothiazole (120-75-2) + benzaldehyde (100-52-7) → 2-[(E)-styryl]benzothiazole (59066-61-4)

Guidance literature:

With sodium hydroxide; In methanol; Heating;

DOI:10.1135/cccc20071069

Reference yield: 93.0%

3-phenyl-propenal (104-55-2) + 2-amino-benzenethiol (137-07-5) → 2-styrylbenzothiazole (1483-30-3,59066-61-4,104505-71-7)

Guidance literature:

With Ag₂CO₃/celite; In ethanol; at 70 ℃; for 3h;

DOI:10.1007/s13738-015-0592-1

Reference yield: 92.0%

(Z)-2-(2-methylthio-2-phenylethenyl)benzothiazole → 2-[(E)-styryl]benzothiazole (59066-61-4)

Guidance literature:

With [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; zinc(II) chloride; zinc; In tetrahydrofuran; at 68 ℃; for 42h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.6b00503

upstream raw materials:

2-Methylbenzothiazole

benzaldehyde

2,3-dihydro-2-phenyl-1,5-benzothiazepin-4(5H)-one

5-Acetyl-2,3-dihydro-2-phenyl-1,5-benzothiazepin-4(5H)-on

Downstream raw materials:

(Z)-2-(2-Phenylethenyl)benzothiazol

2-[(E)-2-phenylvinyl]-3-methyl-1,3-benzothiazol-3-ium iodide

2-[(R)-2-(2-methylphenyl)-2-phenylethyl]benzothiazole

2-[(R)-2-naphthalen-1-yl-2-phenylethyl]benzothiazole