Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)-

Base Information

Chemical Name:Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)-
CAS No.:596122-61-1
Molecular Formula:C17H14Si
Molecular Weight:246.384
Hs Code.:
DSSTox Substance ID:DTXSID10476999
Nikkaji Number:J2.405.950B
Wikidata:Q82309015

Synonyms:Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)-;596122-61-1;DTXSID10476999

Suppliers and Price of Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:5
Exact Mass:246.086476981
Heavy Atom Count:18
Complexity:542

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C#CC#CC#CC#CC1=CC=CC=C1

Technology Process of Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)-

There total 7 articles about Silane, trimethyl(8-phenyl-1,3,5,7-octatetraynyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 919087-35-7
(E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne

: 75-77-4
chloro-trimethyl-silane

: 596122-61-1
1-(trimethylsilyl)-8-phenyl-1,3,5,7-octatetrayne

Guidance literature:: (E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1021/ol0623825

Reference yield: 64.0%

: 596122-60-0
7-phenyl-1-trimethylsilyl-(5-dibromomethylidene)-1,3,6,-heptatriyne

: 596122-61-1
1-(trimethylsilyl)-8-phenyl-1,3,5,7-octatetrayne

Guidance literature:: With n-butyllithium; In hexane; at -78 - -10 ℃;
DOI:10.1002/chem.200204584

Reference yield:

: 919087-27-7
(E)-1-chloro-6-phenyl-1-hexene-3,5-diyne

: 596122-61-1
1-(trimethylsilyl)-8-phenyl-1,3,5,7-octatetrayne

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 74 percent / ZnBr₂ / Pd(PPh₃)4 / tetrahydrofuran; hexane / 6 h / 0 °C

2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 84 percent / tetrahydrofuran; hexane / -78 - 20 °C

With n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.1021/ol0623825