Bromotriphenylstannane

Base Information

• Chemical Name: Bromotriphenylstannane
• CAS No.: 962-89-0
• Molecular Formula: C18H15BrSn
• Molecular Weight: 429.931
• Hs Code.: 2931900090
• European Community (EC) Number: 809-637-6
• DSSTox Substance ID: DTXSID301339477
• Mol file: 962-89-0.mol

Synonyms:bromo(triphenyl)stannane;Bromotriphenylstannane;962-89-0;Triphenyltin Bromide;Stannane, bromotriphenyl-;DTXSID301339477;AKOS024433650

Chemical Property of Bromotriphenylstannane

Chemical Property:

• Vapor Pressure: 7.66E-07mmHg at 25°C
• Boiling Point: 419°Cat760mmHg
• Flash Point: 207.2°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.28050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 429.93792
• Heavy Atom Count: 20
• Complexity: 240

Purity/Quality:

BROMOTRIPHENYLTIN Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)Br

Technology Process of Bromotriphenylstannane

There total 57 articles about Bromotriphenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Ph3SnYb(THF)2(μ-Ph)3Yb(THF)3 → triphenyltin bromide (962-89-0) + diphenyltin(IV) dibromide (4713-59-1) + phenyltin(IV) tribromide (7727-17-5) + ytterbium bromide (13759-89-2)

Guidance literature:

With bromine; In 1,2-dimethoxyethane; byproducts: bromobenzene; bromobenzene detected by GLC;

DOI:10.1016/0022-328X(91)86429-T

Reference yield: 92.5%

(C6H5)3Sn(C5H5) + iodine(I) bromide (7789-33-5) → triphenyltin bromide (962-89-0)

Guidance literature:

In tetrachloromethane; byproducts: C5H5I; (N2); heating (60°C), mixing; distn. (soln. concn., 10 mm Hg), crystn. (petroleum ether); elem. anal.;

Reference yield: 82.0%

triphenyl(p-tolylthiomethyl)tin → triphenyltin bromide (962-89-0)

Guidance literature:

With bromine; In tetrachloromethane; byproducts: CH2(SC6H4Me-p)2, bromoethyl p-tolyl sulphide; dropwise addn. of equimolar amt. of Br2-soln. to cooled soln. of Sn-compd. (stirring); solvent removal (reduced pressure), pptn. on addn. of light petroleum, collection, recrystn. (light petroleum);

DOI:10.1039/DT9760001345

upstream raw materials:

methyl bromide

triphenylstannane

benzyl bromide

triphenyltin chloride

Downstream raw materials:

benzyl bromide

triphenyltin chloride

Ph₃SnSPh

triphenyl(p-tolyl)tin

Refernces

• 1、 Vassilian, Asbed,Bailar, John C. Jr.. "". . p. 389 - 395. Retrieved 1980.
• 2、 Zobel, Bernhard,Lim, Allan E. K.,Dunn, Kerri,Dakternieks, Dainis. "Easy general method for interhalide conversions in organotin compounds". . p. 4889 - 4890. Retrieved 2008/10/08.
• 3、 Lambertsen, Thomas,Schmutzler, Reinhard. "New Observations Concerning the Reactivity of Triorganotin Fluorides". . p. 1583 - 1586. Retrieved 2007/10/03.