diethyldithiocarbamic acid methanethiol

Base Information

• Chemical Name: diethyldithiocarbamic acid methanethiol
• CAS No.: 22158-12-9
• Molecular Formula: C₆H₁₃NS₃
• Molecular Weight: 195.374
• Mol file: 22158-12-9.mol

Synonyms:Peroxycarbamicacid, diethyltrithio-, methyl ester (8CI)

Chemical Property of diethyldithiocarbamic acid methanethiol

Chemical Property:

• Boiling Point: 258.7°Cat760mmHg
• Flash Point: 110.3°C
• PSA: 85.93000
• Density: 1.164g/cm³
• LogP: 2.62430

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of diethyldithiocarbamic acid methanethiol

There total 4 articles about diethyldithiocarbamic acid methanethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

disulfiram (97-77-8) + Dimethyldisulphide (624-92-0) → Methyl-diethylaminocarbotrithioat (22158-12-9)

Guidance literature:

With N-fluorobis(benzenesulfon)imide; In 1,2-dichloro-ethane; at 50 ℃; for 4h; Sealed tube; Schlenk technique;

DOI:10.1016/j.cclet.2021.12.073

Reference yield:

disulfiram (97-77-8) + sodium thiomethoxide (5188-07-8) → Methyl-diethylaminocarbotrithioat (22158-12-9)

Guidance literature:

In N,N-dimethyl-formamide; at 60 ℃;

DOI:10.1016/j.bmcl.2018.03.023

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + N,N-diethylmethanesulfenamide (7257-50-3) → Methyl-diethylaminocarbotrithioat (22158-12-9)

Guidance literature:

Heating;

DOI:10.1021/jo00826a072

upstream raw materials:

carbon disulfide

N,N-diethylmethanesulfenamide

disulfiram

sodium thiomethoxide

Refernces

• 1、 Hu, Qingyue,Li, Zheng-Yi,Song, Mengjie,Sun, Xiaoqiang,Yang, Ke. "NFSI-catalyzed S[sbnd]S bond exchange reaction for the synthesis of unsymmetrical disulfides". supporting information. . Retrieved 2022/01/26.
• 2、 -. "Aminecarbotrithioates". . . Retrieved 2008/06/13.