Methoxy(dimethyl)alumane

Base Information

• Chemical Name: Methoxy(dimethyl)alumane
• CAS No.: 6063-88-3
• Molecular Formula: C3H9AlO
• Molecular Weight: 88.0854
• European Community (EC) Number: 630-877-0
• DSSTox Substance ID: DTXSID20586997
• Mol file: 6063-88-3.mol

Synonyms:Methoxy(dimethyl)alumane;6063-88-3;dimethylaluminum methoxide;DTXSID20586997;NS00120491

Chemical Property of Methoxy(dimethyl)alumane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 88.0468783
• Heavy Atom Count: 5
• Complexity: 20.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Al](C)C

Technology Process of Methoxy(dimethyl)alumane

There total 2 articles about Methoxy(dimethyl)alumane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propanoic acid methyl ester (554-12-1) + trimethylaluminum (75-24-1) → C10H26Al2O + C15H28Al2O2 + methoxydimethylaluminium (6063-88-3)

Guidance literature:

propanoic acid methyl ester; trimethylaluminum; In toluene; at -78 - 20 ℃; for 2h; Inert atmosphere;

In toluene; for 4h; Reflux; Inert atmosphere;

DOI:10.1002/chem.201604553

Reference yield:

trimethylaluminum (75-24-1) + benzeneacetic acid methyl ester (101-41-7) → C15H28Al2O + C12H19AlO2 + methoxydimethylaluminium (6063-88-3)

Guidance literature:

In toluene; at -78 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/chem.201604553

Reference yield: 76.0%

4,4-dimethyl-5-methylene-1,3-dioxolan-2-one (4437-80-3) + 5-decyne (1942-46-7) + methoxydimethylaluminium (6063-88-3) → (E)-5-butyl-2,2,6-trimethyl-3-oxodec-5-enoic acid + (E)-5-butyl-2,6-dimethyldec-5-en-3-one

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In hexane; dimethyl sulfoxide; at 60 ℃; for 24h; stereoselective reaction; Inert atmosphere;

DOI:10.1002/anie.201609338

upstream raw materials:

propanoic acid methyl ester

trimethylaluminum

benzeneacetic acid methyl ester

Downstream raw materials:

4-methyl-2-(1H-pyrazol-1-yl) benzoic acid methyl ester

2-(2-methylphenyl)pyridine

2-(2-Pyridinyl)benzoic Acid

methyl 2-(2-pyridinyl)benzoate