2-(Diphenylmethyl)-1,3-diphenylpropane-1,3-dione

Base Information

• Chemical Name: 2-(Diphenylmethyl)-1,3-diphenylpropane-1,3-dione
• CAS No.: 60999-93-1
• Molecular Formula: C28H22O2
• Molecular Weight: 390.481
• DSSTox Substance ID: DTXSID80515066
• Nikkaji Number: J2.424.674D
• Wikidata: Q82375770
• Mol file: 60999-93-1.mol

Synonyms:60999-93-1;2-(Diphenylmethyl)-1,3-diphenylpropane-1,3-dione;DTXSID80515066

Chemical Property of 2-(Diphenylmethyl)-1,3-diphenylpropane-1,3-dione

Chemical Property:

• PSA: 34.14000
• LogP: 6.20050
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 390.161979940
• Heavy Atom Count: 30
• Complexity: 495

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(C2=CC=CC=C2)C(C(=O)C3=CC=CC=C3)C(=O)C4=CC=CC=C4

Technology Process of 2-(Diphenylmethyl)-1,3-diphenylpropane-1,3-dione

There total 12 articles about 2-(Diphenylmethyl)-1,3-diphenylpropane-1,3-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,1-Diphenylmethanol (91-01-0) + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → 2-benzhydryl-1,3-diphenylpropane-1,3-dione (60999-93-1)

Guidance literature:

With silica gel supported perchloric acid; In toluene; at 70 ℃; for 17h;

DOI:10.1021/jo100517k

Reference yield: 95.0%

benzhydryl ether (574-42-5) + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → 2-benzhydryl-1,3-diphenylpropane-1,3-dione (60999-93-1)

Guidance literature:

With C₁₀H₁₂CoN₃⁽²⁺⁾*2F₆Sb^(1-); In toluene; at 110 ℃; for 3h;

DOI:10.1039/d0ra09778k

Reference yield: 91.0%

N-tosyldiphenylmethylamine (853-83-8) + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → 2-benzhydryl-1,3-diphenylpropane-1,3-dione (60999-93-1)

Guidance literature:

With ytterbium(III) triflate; In nitromethane; at 60 ℃; for 18h;

DOI:10.1016/j.tetlet.2012.01.141

upstream raw materials:

1,3-diphenylpropanedione

Bromodiphenylmethane

1,1-Diphenylmethanol

Diphenylmethane

Downstream raw materials:

1,3,3-triphenylpropan-1-one

N‐(diphenylmethyl)‐4‐nitroaniline

N-(bis(4-tert-butylphenyl)methyl)-4-nitroaniline

[bis-(4-chlorophenyl)methyl]-(4-nitrophenyl)amine