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Usage

Uses

Used in Organic Electronics:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is utilized as a component in organic electronics due to its high thermal and chemical stability, which is essential for the performance and longevity of electronic devices.
Used in Nanotechnology:
In the nanotechnology industry, 1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene serves as a structural element in nanoscale devices and materials, taking advantage of its stability and symmetrical properties to create reliable and precise nanostructures.
Used as an Electron Transfer Bridge:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is employed as an electron transfer bridge in molecular systems, capitalizing on its ability to facilitate electron movement, which is crucial for the function of certain molecular electronic devices and sensors.
Used in Molecular Devices:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is used in the development of molecular devices,得益于其刚性结构和对称性，它有潜力作为构建复杂分子机器和逻辑门的组成部分。
Used in Research of Complex Organic Compounds:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is also used in academic and research settings to study the properties and behaviors of complex organic compounds, providing insights into the structural and functional aspects of organic chemistry.

Upstream product

• 10467-10-4 ethylmagnesium iodide 
• 60-29-7 diethyl ether 
• 954-67-6 benzhydryl acetate 
• 79-37-8 oxalyl dichloride 
• 91-01-0 1,1-Diphenylmethanol 
• 6296-95-3 1,1,2-triphenyl-1,2-ethanediol 
• 101-81-5 Diphenylmethane 
• 117-34-0 2,2-diphenylacetic acid 
• 71964-91-5 benzhydryl-trimethyl-ammonium; bromide 
• 100-52-7 benzaldehyde 
• 98-88-4 benzoyl chloride 
• 56-23-5 tetrachloromethane 
• 122-04-3 4-nitro-benzoyl chloride 
• 57-13-6 urea 

Downstream Products

• 119-61-9 benzophenone 
• 101-81-5 Diphenylmethane 
• 858848-88-1 2,5-bisbenzhydrylthiophene 
• 26059-49-4 benzyl diphenylmethyl ether 
• 7495-83-2 n-butyl diphenylmethyl ether 
• 954-67-6 benzhydryl acetate 
• 725239-78-1 α-pehnylbenzenemethyl trichloroacetate 
• 519-73-3 triphenylmethane 
• 632-50-8 1,1,2,2-tetraphenylethane 
• 612-00-0 1,1'-ethylidenebis-benzene 
• 55363-57-0 4-n-butylbenzophenone 
• 5384-63-4 1,1-diphenylpentanol 
• 854258-95-0 (1,1-diphenyl-pentyl)-methyl ether 
• 59137-63-2 (2-butyl-phenyl)-phenyl-methanone 

Relevant academic research and scientific papers

INTERMEDIATES IN THE LEUCKART REACTION OF BENZOPHENONE WITH FORMAMIDE

The isolation of benzhydrol and its ether in conjunction with N-formylbenzhydrylamine in the Leuckart reaction of benzophenone is reported; it is postulated that this alcohol is a possible intermediate in the reaction.

Room temperature reactions of XeF2 with phenyl substituted alcohols

Benzyl alkohol and its analogues with a non-activated benzene ring are transformed to fluoromethoxy derivatives by reaction with XeF2. The same reaction with diphenyl methanol gives di diphenylmethylether, while 2-phenyl-2-propanol transforms to 2,4-diphenyl-4-methyl-1-pentene.

An expedient, efficient and solvent-free synthesis of T3P-mediated amidation of benzhydrols with poorly reactive N-nucleophiles under MW irradiation

An expedient, efficient, economical, environmentally benign, and solvent free amidation protocol of benzhydrols with less reactive nitrogen nucleophiles assisted by propylphosphonic anhydride (T3P) under microwave irradiation has been developed. The methodology has been deployed for a wide range of heterocycles and electron-withdrawing & electron-donating groups. The protocol resulted in good to excellent yields under the given conditions (26 examples, 68-93% yield).

Synthetic method of borane-catalyzed symmetric ether

The invention provides a borane-catalyzed symmetric ether synthesis method, which is characterized in that alcohol is used as a raw material, and under the catalysis of B(2,6-Cl2C6H3) (p-HC6F4) 2, etherification reaction is carried out through intermolecular dehydration to generate ether. The reaction process is simple, mild, pollution-free and efficient.

Monoallylation and benzylation of dicarbonyl compounds with alcohols catalysed by a cationic cobalt(iii) compound

Monoallylation and monoalkylation of diketones and β-keto esters with allylic and benzylic alcohols catalysed by [Cp*Co(CH3CN)3][SbF6]2(I) are reported. The method does not require any additive and affords regioselective products. The mechanistic investigations were done byin situ1H NMR spectroscopy as well as control experiments. It has been shown that reactions proceedviaη3-allyl complex formation or ally ether intermediate. The alkylation takes placeviaonly ether intermediate. The resulting allylated and alkylated products have been used for the synthesis of eleven new trisubstituted pyrazoles and one pyrazolone.

Deoxygenation of tertiary and secondary alcohols with sodium borohydride, trimethylsilyl chloride, and potassium iodide in acetonitrile

The deoxygenation of tertiary and secondary alcohols to give the corresponding alkanes is conventionally performed using an organosilane and a strong acid. In this study, a deoxygenation method was developed for tertiary and secondary alcohols, using trimethylsilane and trimethylsilyl iodide generated in situ from sodium borohydride and trimethylsilyl chloride, and trimethylsilyl chloride and potassium iodide, respectively. With our method, tertiary and secondary alcohols, which provided stable carbocations, were converted into the corresponding alkanes. This paper also presents the optimization of the reaction conditions, the reaction mechanism, as well as the scope and limitations of the method.

Mechanochemical Nucleophilic Substitution of Alcohols via Isouronium Intermediates**

An expansion of the solvent-free synthetic toolbox is essential for advances in the sustainable chemical industry. Mechanochemical reactions offer a superior safety profile and reduced amount of waste compared to conventional solvent-based synthesis. Here

Microwave-Assisted Condensation of Benzylic Alcohols and Alkynes Promoted by Zinc Halides: Concise Access to Alkenyl Halides

A simple Lewis acid-mediated route for the synthesis of alkenyl halides are described under microwave-assisted conditions. The reaction proceeds through the condensation between secondary alcohols and terminal acetylenes and regioselective hydrohalogenati

Arylboronic Acid Catalyzed C-Alkylation and Allylation Reactions Using Benzylic Alcohols

The arylboronic acid catalyzed dehydrative C-alkylation of 1,3-diketones and 1,3-ketoesters using secondary benzylic alcohols as the electrophile is reported, forming new C-C bonds (19 examples, up to 98% yield) with the release of water as the only byproduct. The process is also applicable to the allylation of benzylic alcohols using allyltrimethylsilane as the nucleophile (12 examples, up to 96% yield).

Photoelimination of Nitrogen from Diazoalkanes: Involvement of Higher Excited Singlet States in the Carbene Formation

Although diazoalkanes are important carbene precursors in organic synthesis, a comprehensive mechanism of photochemical formation of carbenes from diazoalkanes has not been proposed. Synergies of experiments and computations demonstrate the involvement of higher excited singlet states in the photochemistry of diazoalkanes. In all investigated diazoalkanes, excitation to S1 results in nonreactive internal conversion to S0. On the contrary, excitation to higher-lying singlet states (Sn, n > 1) drives the reaction toward a different segment of the S1/S0 conical intersection seam and results in nitrogen elimination and formation of carbenes.