574-42-5

Usage

Uses

Used in Organic Electronics:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is utilized as a component in organic electronics due to its high thermal and chemical stability, which is essential for the performance and longevity of electronic devices.
Used in Nanotechnology:
In the nanotechnology industry, 1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene serves as a structural element in nanoscale devices and materials, taking advantage of its stability and symmetrical properties to create reliable and precise nanostructures.
Used as an Electron Transfer Bridge:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is employed as an electron transfer bridge in molecular systems, capitalizing on its ability to facilitate electron movement, which is crucial for the function of certain molecular electronic devices and sensors.
Used in Molecular Devices:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is used in the development of molecular devices,得益于其刚性结构和对称性，它有潜力作为构建复杂分子机器和逻辑门的组成部分。
Used in Research of Complex Organic Compounds:
1,1',1'',1'''-(Oxydimethylidyne)Tetrakis Benzene is also used in academic and research settings to study the properties and behaviors of complex organic compounds, providing insights into the structural and functional aspects of organic chemistry.

Upstream product

• 10467-10-4 ethylmagnesium iodide 
• 60-29-7 diethyl ether 
• 954-67-6 benzhydryl acetate 
• 917-64-6 methyl magnesium iodide 
• 91-01-0 1,1-Diphenylmethanol 
• 50-00-0 formaldehyd 
• 119-61-9 benzophenone 
• 79-37-8 oxalyl dichloride 
• 101-81-5 Diphenylmethane 
• 117-34-0 2,2-diphenylacetic acid 
• 464-72-2 tetraphenylethane-1,2-diol 
• 71964-91-5 benzhydryl-trimethyl-ammonium; bromide 
• 100-52-7 benzaldehyde 
• 98-88-4 benzoyl chloride 

Downstream Products

• 119-61-9 benzophenone 
• 101-81-5 Diphenylmethane 
• 55504-21-7 ((tert-butylperoxy)methylene)dibenzene 
• 2294-94-2 1,1,1,2-tetraphenylethane 
• 632-50-8 1,1,2,2-tetraphenylethane 
• 632-51-9 1,1,2,2-tetraphenylethylene 
• 20614-54-4 (hydroperoxymethylene)dibenzene 
• 412300-97-1 2,2'-(1,3-diphenyl-2-oxa-propanediyl)-di-benzoic acid 
• 10060-17-0 (diphenylmethyl)potassium 
• 90-99-3 diphenylchloromethane 
• 26059-49-4 benzyl diphenylmethyl ether 
• 7495-83-2 n-butyl diphenylmethyl ether 
• 954-67-6 benzhydryl acetate 
• 725239-78-1 α-pehnylbenzenemethyl trichloroacetate 

Relevant academic research and scientific papers

INTERMEDIATES IN THE LEUCKART REACTION OF BENZOPHENONE WITH FORMAMIDE

The isolation of benzhydrol and its ether in conjunction with N-formylbenzhydrylamine in the Leuckart reaction of benzophenone is reported; it is postulated that this alcohol is a possible intermediate in the reaction.

Room temperature reactions of XeF2 with phenyl substituted alcohols

Benzyl alkohol and its analogues with a non-activated benzene ring are transformed to fluoromethoxy derivatives by reaction with XeF2. The same reaction with diphenyl methanol gives di diphenylmethylether, while 2-phenyl-2-propanol transforms to 2,4-diphenyl-4-methyl-1-pentene.

An expedient, efficient and solvent-free synthesis of T3P-mediated amidation of benzhydrols with poorly reactive N-nucleophiles under MW irradiation

An expedient, efficient, economical, environmentally benign, and solvent free amidation protocol of benzhydrols with less reactive nitrogen nucleophiles assisted by propylphosphonic anhydride (T3P) under microwave irradiation has been developed. The methodology has been deployed for a wide range of heterocycles and electron-withdrawing & electron-donating groups. The protocol resulted in good to excellent yields under the given conditions (26 examples, 68-93% yield).

Synthetic method of borane-catalyzed symmetric ether

The invention provides a borane-catalyzed symmetric ether synthesis method, which is characterized in that alcohol is used as a raw material, and under the catalysis of B(2,6-Cl2C6H3) (p-HC6F4) 2, etherification reaction is carried out through intermolecular dehydration to generate ether. The reaction process is simple, mild, pollution-free and efficient.

Monoallylation and benzylation of dicarbonyl compounds with alcohols catalysed by a cationic cobalt(iii) compound

Monoallylation and monoalkylation of diketones and β-keto esters with allylic and benzylic alcohols catalysed by [Cp*Co(CH3CN)3][SbF6]2(I) are reported. The method does not require any additive and affords regioselective products. The mechanistic investigations were done byin situ1H NMR spectroscopy as well as control experiments. It has been shown that reactions proceedviaη3-allyl complex formation or ally ether intermediate. The alkylation takes placeviaonly ether intermediate. The resulting allylated and alkylated products have been used for the synthesis of eleven new trisubstituted pyrazoles and one pyrazolone.

Deoxygenation of tertiary and secondary alcohols with sodium borohydride, trimethylsilyl chloride, and potassium iodide in acetonitrile

The deoxygenation of tertiary and secondary alcohols to give the corresponding alkanes is conventionally performed using an organosilane and a strong acid. In this study, a deoxygenation method was developed for tertiary and secondary alcohols, using trimethylsilane and trimethylsilyl iodide generated in situ from sodium borohydride and trimethylsilyl chloride, and trimethylsilyl chloride and potassium iodide, respectively. With our method, tertiary and secondary alcohols, which provided stable carbocations, were converted into the corresponding alkanes. This paper also presents the optimization of the reaction conditions, the reaction mechanism, as well as the scope and limitations of the method.

Mechanochemical Nucleophilic Substitution of Alcohols via Isouronium Intermediates**

An expansion of the solvent-free synthetic toolbox is essential for advances in the sustainable chemical industry. Mechanochemical reactions offer a superior safety profile and reduced amount of waste compared to conventional solvent-based synthesis. Here

Microwave-Assisted Condensation of Benzylic Alcohols and Alkynes Promoted by Zinc Halides: Concise Access to Alkenyl Halides

A simple Lewis acid-mediated route for the synthesis of alkenyl halides are described under microwave-assisted conditions. The reaction proceeds through the condensation between secondary alcohols and terminal acetylenes and regioselective hydrohalogenati

Method for synthesizing ether by catalyzing alcohol through trimethyl halosilane

The invention discloses a method for synthesizing ether by catalyzing alcohol through trimethyl halosilane. According to the method, under the conditions of air or nitrogen atmosphere, no solvent andno transition metal catalyst, an alcohol compound is directly used as a raw material, trimethyl halosilane is used as a catalyst, and symmetric or asymmetric ether is synthesized through one-step selective dehydration reaction. According to the method, the use of strong acid, strong base and organic primary halides with high toxicity, instability and higher price is avoided, the synthesis steps are shortened, the synthesis efficiency is improved, the reaction has good selectivity, and a target ether product can be obtained preferentially.

Switchable iridium hydride catalysts for controlling selectivity of alcohol oxidation

Novel pyridyl-triazolylidene iridium(III) hydride complexes have been synthesized through modification of the analogous iridium chloride complexes. The dehydration of alcohols was used to probe the catalytic potential of the iridium chloride compounds and the influence of the electronic modification on the pyridyl-triazolylidene ligand scaffolds. The incorporation of electron donor substituents on the triazolylidene heterocycle considerably enhanced the catalytic activity of the coordinated iridium center towards the catalytic dehydration of alcohols. Moreover, the iridium hydride compounds are switchable catalysts that perform either alcohol dehydration or dehydrogenation. Their selectivity was predictably triggered by the presence or absence of HPF6 in the catalytic reaction.