Trimethyl[(3-methylcyclohexa-1,3-dien-1-yl)oxy]silane

Base Information

• Chemical Name: Trimethyl[(3-methylcyclohexa-1,3-dien-1-yl)oxy]silane
• CAS No.: 61140-45-2
• Molecular Formula: C₁₀H₁₈OSi
• Molecular Weight: 182.338
• DSSTox Substance ID: DTXSID90540905
• Nikkaji Number: J3.292.112D
• Wikidata: Q82417039
• Mol file: 61140-45-2.mol

Synonyms:61140-45-2;Trimethyl[(3-methylcyclohexa-1,3-dien-1-yl)oxy]silane;DTXSID90540905

Chemical Property of Trimethyl[(3-methylcyclohexa-1,3-dien-1-yl)oxy]silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 182.112691728
• Heavy Atom Count: 12
• Complexity: 221

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CCCC(=C1)O[Si](C)(C)C

Technology Process of Trimethyl[(3-methylcyclohexa-1,3-dien-1-yl)oxy]silane

There total 2 articles about Trimethyl[(3-methylcyclohexa-1,3-dien-1-yl)oxy]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + 3-methylcyclohexen-2-one (1193-18-6) → Trimethyl-(3-methyl-cyclohexa-1,3-dienyloxy)-silane (61140-45-2) + 3-Methylen-1-(trimethylsiloxy)-1-cyclohexen (80239-26-5)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane; Yield given. Multistep reaction. Yields of byproduct given; 1.) DMF, THF, -78 deg C, 2 h; 2.) DMF, THF, 20 min, r.t.;

DOI:10.1246/cl.1985.647

Reference yield:

chloro-trimethyl-silane (75-77-4) + 3-methylcyclohex-3-en-1-one (31883-98-4) → Trimethyl-(3-methyl-cyclohexa-1,3-dienyloxy)-silane (61140-45-2)

Guidance literature:

Multistep reaction; (i) iPr₂NLi, (ii) /BRN= 1209232/;

DOI:10.1021/jo00426a026

Reference yield:

Trimethyl-(3-methyl-cyclohexa-1,3-dienyloxy)-silane (61140-45-2) + lead(IV) tetrabenzoate (7717-48-8,15907-04-7,873-54-1) → 2-Benzoyloxy-3-methyl-3-cyclohexen-1-on (61140-54-3)

Guidance literature:

Multistep reaction; (i), (ii) Et₃N*HF;

DOI:10.1021/jo00426a026

upstream raw materials:

chloro-trimethyl-silane

3-methylcyclohexen-2-one

3-methylcyclohex-3-en-1-one

Downstream raw materials:

2-Benzoyloxy-3-methyl-3-cyclohexen-1-on