N,N-diphenylnaphthalen-1-amine

Base Information

• Chemical Name: N,N-diphenylnaphthalen-1-amine
• CAS No.: 61231-45-6
• Molecular Formula: C22H17N
• Molecular Weight: 295.384
• Hs Code.: 2921499090
• DSSTox Substance ID: DTXSID90464516
• Nikkaji Number: J1.918.763B
• Wikidata: Q82289864
• Mol file: 61231-45-6.mol

Synonyms:N,N-diphenylnaphthalen-1-amine;61231-45-6;N,N-diphenyl-1-naphthylamine;naphthyldiphenylamine;SCHEMBL272955;DTXSID90464516;FGGAOQTXQHKQOW-UHFFFAOYSA-N;AKOS015964538;3-(2,3-Dichlorophenyl)-1-(3,4-dichlorophenyl)-1-hydroxyurea

Chemical Property of N,N-diphenylnaphthalen-1-amine

Chemical Property:

• Melting Point: 142°C
• Refractive Index: 1.8500 (estimate)
• Boiling Point: 427.06°C (rough estimate)
• PSA: 3.24000
• Density: 1.0541 (rough estimate)
• LogP: 6.30960
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 295.136099547
• Heavy Atom Count: 23
• Complexity: 335

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N(C2=CC=CC=C2)C3=CC=CC4=CC=CC=C43

Technology Process of N,N-diphenylnaphthalen-1-amine

There total 19 articles about N,N-diphenylnaphthalen-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

bromobenzene (108-86-1,52753-63-6) + 1-amino-naphthalene (134-32-7) → 1-(N,N-diphenylamino)naphthalene (61231-45-6)

Guidance literature:

With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate; In neat (no solvent); at 110 ℃; for 12h; Inert atmosphere; Green chemistry;

DOI:10.1002/ejoc.201501616

Reference yield: 95.0%

1-Bromonaphthalene (90-11-9) + diphenylamine (122-39-4) → 1-(N,N-diphenylamino)naphthalene (61231-45-6)

Guidance literature:

With palladium diacetate; sodium t-butanolate; ruphos; In neat (no solvent); at 110 ℃; for 12h; Green chemistry;

DOI:10.1002/ejoc.201402077

Reference yield: 94.0%

1-Bromonaphthalene (90-11-9) + N-(trimethylsilyl)-diphenylamine (17425-91-1) → 1-(N,N-diphenylamino)naphthalene (61231-45-6)

Guidance literature:

With cesium fluoride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; XPhos; at 100 ℃; for 3h; Inert atmosphere;

DOI:10.1246/cl.131075

upstream raw materials:

1-Bromonaphthalene

diphenylamine

N-(3-trifluoromethylphenyl)aniline

1-Iodonaphthalene

Downstream raw materials:

4,4'-bis[N-(1-naphthyl)-N-phenylamino] biphenyl