Technology Process of Cycloheptanol, 1-[(1Z)-2-[tris(phenylmethyl)stannyl]ethenyl]-
There total 1 articles about Cycloheptanol, 1-[(1Z)-2-[tris(phenylmethyl)stannyl]ethenyl]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
dibenzoyl peroxide;
In
diethyl ether;
under N2; to soln. of tribenzylstannane and 1-ethynyl-1-cycloheptanol (1:1 mol) in Et2O added dibenzoyl peroxide; stirred 20 h with condenser equipped with CaCl2-tube; Et2O evapd.; crystn. from EtOH; filtered from (PhCH2)3SnSn(CH2Ph)3; elem. anal.;
DOI:10.1081/SIM-120021941
- Guidance literature:
-
In
tetrachloromethane;
soln. of Br2 (2 mol) in CCl4 added dropwise at -10°C to soln. of (Z)-1-(2-(tribenzylstannyl)vinyl)-1-cycloheptanol (1 mol) in CCl4 with stirring; after addn. of Br2 mixt. was kept 10 h at room temp.; solvent evapd.; crystn. from cyclohexane; elem. anal.;
DOI:10.1081/SIM-120021941
- Guidance literature:
-
In
tetrachloromethane;
soln. of ICl (1 mol) in CCl4 added dropwise at -5°C to soln. of (Z)-1-(2-(tribenzylstannyl)vinyl)-1-cycloheptanol (1 mol) in CCl4 with stirring; after addn. of ICl react. mixt. was kept 4 h at room temp.; solvent evapd.; crystn. from cyclohexane/CCl4 (1:1 v/v); elem. anal.;
DOI:10.1081/SIM-120021941
