ethyl (5Z)-5-[(4-ethoxycarbonyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-2,4-dimethylpyrrole-3-carboxylate;nickel(2+)

Base Information

• Chemical Name: ethyl (5Z)-5-[(4-ethoxycarbonyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-2,4-dimethylpyrrole-3-carboxylate;nickel(2+)
• CAS No.: 14074-96-5
• Molecular Formula: C₃₈H₄₆N₄NiO₈
• Molecular Weight: 745.495
• NSC Number: 17448
• Mol file: 14074-96-5.mol

Synonyms:NSC17448;NSC-17448;14074-96-5

Chemical Property of ethyl (5Z)-5-[(4-ethoxycarbonyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-2,4-dimethylpyrrole-3-carboxylate;nickel(2+)

Chemical Property:

• Vapor Pressure: 6.55E-11mmHg at 25°C
• Boiling Point: 519.9°Cat760mmHg
• Flash Point: 268.2°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 12
• Exact Mass: 744.266906
• Heavy Atom Count: 51
• Complexity: 1310

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)C1=C(C(=CC2=C(C(=C([N-]2)C)C(=O)OCC)C)N=C1C)C.CCOC(=O)C1=C(C(=CC2=C(C(=C([N-]2)C)C(=O)OCC)C)N=C1C)C.[Ni+2]
• Isomeric SMILES: CCOC(=O)C1=C(/C(=C/C2=C(C(=C([N-]2)C)C(=O)OCC)C)/N=C1C)C.CCOC(=O)C1=C(/C(=C/C2=C(C(=C([N-]2)C)C(=O)OCC)C)/N=C1C)C.[Ni+2]

Technology Process of ethyl (5Z)-5-[(4-ethoxycarbonyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-2,4-dimethylpyrrole-3-carboxylate;nickel(2+)

There total 4 articles about ethyl (5Z)-5-[(4-ethoxycarbonyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-2,4-dimethylpyrrole-3-carboxylate;nickel(2+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) + 3,5,3',5'-tetramethyl-4,4'-dicarbethoxy-dipyrromethene-hydrogen chloride (14622-24-3) → {Ni(C19H23N2O4)2} (14074-96-5)

Guidance literature:

With sodium acetate; In ethanol; addn. of hot satd. Ni acetate soln. to warm suspension of C19H24N2O4 hydrochloride in alc. (contg. satd. Na acetate soln.), cooling down;; pptn., recrystn. from alc.;;

DOI:10.1038/145862a0

Reference yield:

3,3',5,5'-tetramethyl-4,4'-dicarboethoxydipyrromethene (2407-87-6) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → {Ni(C19H23N2O4)2} (14074-96-5)

Guidance literature:

With sodium acetate; In ethanol; addn. of satd. Ni acetate soln. and Na acetate soln. to alc. C19H24N2O4 soln., addn. of H2O after 30 min;; recrystn. from petroleum ether or alc.;;

DOI:10.1039/JR9380000368

Reference yield:

3,3',5,5'-tetramethyl-4,4'-dicarboethoxydipyrromethene (2407-87-6) + nickel(II) nitrate → {Ni(C19H23N2O4)2} (14074-96-5)

Guidance literature:

With sodium acetate; In ethanol; prepn. from alc. soln. of C19H24N2O4 and hot Ni(NO3)2 soln. with addn. of Na acetate soln.;; pptn., recrystn. from acetone;;

upstream raw materials:

3,3',5,5'-tetramethyl-4,4'-dicarboethoxydipyrromethene

nickel diacetate

3,5,3',5'-tetramethyl-4,4'-dicarbethoxy-dipyrromethene-hydrogen chloride

nickel dichloride