Benzenepropanoic acid, b-chloro-a-oxo-, 1,1-dimethylethyl ester

Base Information

Chemical Name:Benzenepropanoic acid, b-chloro-a-oxo-, 1,1-dimethylethyl ester
CAS No.:62148-70-3
Molecular Formula:C13H15ClO3
Molecular Weight:254.713
Hs Code.:

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Chemical Property of Benzenepropanoic acid, b-chloro-a-oxo-, 1,1-dimethylethyl ester

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Technology Process of Benzenepropanoic acid, b-chloro-a-oxo-, 1,1-dimethylethyl ester

There total 2 articles about Benzenepropanoic acid, b-chloro-a-oxo-, 1,1-dimethylethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 49653-47-6
tert-butyl 2,2-dichloroacetate

: 100-52-7
benzaldehyde

: 2-chloro-3-phenyl-oxirane-2-carboxylic acid tert-butyl ester

: 62148-70-3
tert-butyl 3-chloro-2-oxo-3-phenylpropionate

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at -80 - 20 ℃; for 17h;
DOI:10.1007/s11172-006-0440-7

Reference yield:

: 49653-47-6
tert-butyl 2,2-dichloroacetate

: 100-52-7
benzaldehyde

: 62148-70-3
tert-butyl 3-chloro-2-oxo-3-phenylpropionate

Guidance literature:: tert-butyl 2,2-dichloroacetate; benzaldehyde; With potassium tert-butylate; In tetrahydrofuran; at 0 - 20 ℃; for 18h;

With tetrabutyl-ammonium chloride; for 12h;
DOI:10.1021/ja511701j

Reference yield: 93.0%

: 62148-70-3
tert-butyl 3-chloro-2-oxo-3-phenylpropionate

: 1415392-14-1
(2S,3R)-tert-butyl 3-chloro-2-hydroxy-3-phenylpropanoate

Guidance literature:: With formic acid; C₄₂H₄₀ClN₂O₂RuS; triethylamine; In N,N-dimethyl-formamide; at 0 ℃; for 10h; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja3102709