Bicyclo[2.2.1]heptane-2-carboxylic acid, 1,7,7-trimethyl-

Base Information

Chemical Name:Bicyclo[2.2.1]heptane-2-carboxylic acid, 1,7,7-trimethyl-
CAS No.:62280-85-7
Molecular Formula:C11H18O2
Molecular Weight:182.263
Hs Code.:

Synonyms:1,7,7-Trimethyl-norbornan-2-carbonsaeure;1,7,7-trimethyl-norbornane-2-carboxylic acid;1,7,7-trimethyl-norbornane-2ξ-carboxylic acid;Camphancarbonsaeure-(2);1.7.7-Trimethyl-bicyclo-[1.2.2]-heptan-carbonsaeure-(2);

Suppliers and Price of Bicyclo[2.2.1]heptane-2-carboxylic acid, 1,7,7-trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Bicyclo[2.2.1]heptane-2-carboxylic acid, 1,7,7-trimethyl-

Chemical Property:

PSA：37.30000
LogP:2.53340

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Bicyclo[2.2.1]heptane-2-carboxylic acid, 1,7,7-trimethyl-

There total 15 articles about Bicyclo[2.2.1]heptane-2-carboxylic acid, 1,7,7-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 170509-18-9
1,8,8-trimethylbicyclo<3.2.1>oct-6-en-2-one

: 6703-30-6,6811-76-3,13705-55-0,13705-56-1,18444-68-3,52491-97-1,62280-85-7,85954-56-9,85954-57-0
exo-1,7,7-trimethylbicyclo<2.2.1>heptane-2-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / H₂ / 5percent Pt-C / ethyl acetate / 2.5 h

2: 96 percent / t-BuOK, 2,4,6-triisopropylbenzenesulfonyl azide / tetrahydrofuran / 0.33 h / -78 °C

3: aq. NaHCO₃ / tetrahydrofuran / 1 h / Irradiation

With 2,4,6-Triisopropylbenzenesulfonyl azide; potassium tert-butylate; hydrogen; sodium hydrogencarbonate; platinum on activated charcoal; In tetrahydrofuran; ethyl acetate;
DOI:10.1246/bcsj.68.2687

Reference yield:

: 170509-18-9
1,8,8-trimethylbicyclo<3.2.1>oct-6-en-2-one

: 6703-30-6,6811-76-3,13705-55-0,13705-56-1,18444-68-3,52491-97-1,62280-85-7,85954-56-9,85954-57-0
Bornylcarbonsaeure

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / H₂ / 5percent Pt-C / ethyl acetate / 2.5 h

2: 96 percent / t-BuOK, 2,4,6-triisopropylbenzenesulfonyl azide / tetrahydrofuran / 0.33 h / -78 °C

3: aq. NaHCO₃ / tetrahydrofuran / 1 h / Irradiation

With 2,4,6-Triisopropylbenzenesulfonyl azide; potassium tert-butylate; hydrogen; sodium hydrogencarbonate; platinum on activated charcoal; In tetrahydrofuran; ethyl acetate;
DOI:10.1246/bcsj.68.2687

Reference yield:

: 1,8,8-Trimethyl-bicyclo[3.2.1]oct-6-en-2-ol

: 6703-30-6,6811-76-3,13705-55-0,13705-56-1,18444-68-3,52491-97-1,62280-85-7,85954-56-9,85954-57-0
exo-1,7,7-trimethylbicyclo<2.2.1>heptane-2-carboxylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / p-toluenesulfonic acid monohydrate / benzene / 0.5 h / Heating

2: 94 percent / H₂ / 5percent Pt-C / ethyl acetate / 2.5 h

3: 96 percent / t-BuOK, 2,4,6-triisopropylbenzenesulfonyl azide / tetrahydrofuran / 0.33 h / -78 °C

4: aq. NaHCO₃ / tetrahydrofuran / 1 h / Irradiation

With 2,4,6-Triisopropylbenzenesulfonyl azide; potassium tert-butylate; hydrogen; sodium hydrogencarbonate; toluene-4-sulfonic acid; platinum on activated charcoal; In tetrahydrofuran; ethyl acetate; benzene;
DOI:10.1246/bcsj.68.2687