(1S,5R,13R,14S,17R)-4-methyl-12-oxa-4-azapentacyclo[9.6.1.0~1,13~.0~5,17~.0~7,18~]octadeca-7(18),8,10,15-tetraene-10,14-diyl diacetate - (1R,5R,8R)-8-[(8S,9S,10R,13S,14S,17R)-10,13-dimethyl-1-oxo-4,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a

Base Information

• Chemical Name: (1S,5R,13R,14S,17R)-4-methyl-12-oxa-4-azapentacyclo[9.6.1.0~1,13~.0~5,17~.0~7,18~]octadeca-7(18),8,10,15-tetraene-10,14-diyl diacetate - (1R,5R,8R)-8-[(8S,9S,10R,13S,14S,17R)-10,13-dimethyl-1-oxo-4,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a
• CAS No.: 160955-51-1
• Molecular Formula: C₂₉H₄₂O₇
• Molecular Weight: 502.648
• Mol file: 160955-51-1.mol

Synonyms:WithametelinH

Chemical Property of (1S,5R,13R,14S,17R)-4-methyl-12-oxa-4-azapentacyclo[9.6.1.0~1,13~.0~5,17~.0~7,18~]octadeca-7(18),8,10,15-tetraene-10,14-diyl diacetate - (1R,5R,8R)-8-[(8S,9S,10R,13S,14S,17R)-10,13-dimethyl-1-oxo-4,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1S,5R,13R,14S,17R)-4-methyl-12-oxa-4-azapentacyclo[9.6.1.0~1,13~.0~5,17~.0~7,18~]octadeca-7(18),8,10,15-tetraene-10,14-diyl diacetate - (1R,5R,8R)-8-[(8S,9S,10R,13S,14S,17R)-10,13-dimethyl-1-oxo-4,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a

There total 3 articles about (1S,5R,13R,14S,17R)-4-methyl-12-oxa-4-azapentacyclo[9.6.1.0~1,13~.0~5,17~.0~7,18~]octadeca-7(18),8,10,15-tetraene-10,14-diyl diacetate - (1R,5R,8R)-8-[(8S,9S,10R,13S,14S,17R)-10,13-dimethyl-1-oxo-4,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-1H-cyclopenta[a which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

withametelin (113430-43-6) → withametelin H (160955-51-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 30percent aq. H₂O₂ / 1 h

2: aq. NaOH / 0.25 h / Heating

3: 25 mg / 70percent aq. HClO₄ / Ambient temperature

With sodium hydroxide; perchloric acid; dihydrogen peroxide;

Reference yield:

withmetelin G menoformate (151516-14-2) → withametelin H (160955-51-1)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. NaOH / 0.25 h / Heating

2: 25 mg / 70percent aq. HClO₄ / Ambient temperature

With sodium hydroxide; perchloric acid;

Reference yield:

methanol (67-56-1) + (5α,6β)-21,24-epoxy-5,6-dihydroxy-1-oxowitha-5,25(27)-dienolide (151344-95-5) → withametelin H (160955-51-1)

Guidance literature:

With perchloric acid; Ambient temperature;

upstream raw materials:

methanol

(5α,6β)-21,24-epoxy-5,6-dihydroxy-1-oxowitha-5,25(27)-dienolide

withametelin

withmetelin G menoformate

Refernces