HEXAAMMINERUTHENIUM(II) CHLORIDE

Base Information

• Chemical Name: HEXAAMMINERUTHENIUM(II) CHLORIDE
• CAS No.: 15305-72-3
• Molecular Formula: 2Cl*H₁₈N₆Ru
• Molecular Weight: 274.159
• Hs Code.: 28439090
• Mol file: 15305-72-3.mol

Synonyms:Hexaamminerutheniumdichloride (7CI); Ruthenium(2+), hexaammine-, dichloride (8CI); Ruthenium(2+), hexaammine-,dichloride, (OC-6-11)- (9CI); Hexaamineruthenium(2+) dichloride;Hexaammineruthenium(2+) dichloride; Hexaammineruthenium(II) chloride;Hexammineruthenium dichloride; Ruthenium hexaammine dichloride; Ruthenium(II)hexaammine dichloride

Chemical Property of HEXAAMMINERUTHENIUM(II) CHLORIDE

Chemical Property:

• Melting Point: 300°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 19.44000
• Density: g/cm³
• LogP: -4.04860
• Storage Temp.: Refrigerator (+4°C)
• Sensitive.: Air Sensitive
• Solubility.: H2O: slightly soluble(lit.)

Purity/Quality:

98%,99%, ^*data from raw suppliers

Hexaammineruthenium(II) chloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Hexaammineruthenium(ii) chloride is an inorganic complex and has been used in the study of ion transfer coupling with electron transfer by hydrophilic droplet electroides.

Technology Process of HEXAAMMINERUTHENIUM(II) CHLORIDE

There total 7 articles about HEXAAMMINERUTHENIUM(II) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

ammonia (7664-41-7) + ruthenium(III)chloride (10049-08-8,63767-78-2) → hexaammineruthenium(II) chloride (19052-44-9,15305-72-3)

Guidance literature:

With Zn; NH₄Cl; In water; prepn. from RuCl3 and aq. NH3 and Zn metal in the presence of NH4Cl according to F. M. Lever and A.R. Powell, J. Chem.Soc. A 9, 1477 (1969);

DOI:10.1134/S0036023607010123

Reference yield:

hexammine ruthenium(III) chloride (14282-91-8) → hexaammineruthenium(II) chloride (19052-44-9,15305-72-3)

Guidance literature:

With mercury; zinc; In water; Ru-complex dissolved in distd., deionized water, soln. deoxygenated with Ar gas, Zn/Hg added, 15 min.;

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) + ammonium chloride + ammonia (7664-41-7) → hexaammineruthenium(II) chloride (19052-44-9,15305-72-3)

Guidance literature:

With zinc; In hydrogenchloride; ammonia; boiling 15 g RuCl3*3H2O in 50 ml concd. HCl and stirring for 1 h; addn. of a stirred soln. of 5 g NH4Cl in 150 ml aq. NH3 (density 0.880) drop by drop; addn. of 7.5 g Zn dust in small portions (0.5 g); formation of a yellow soln. on boiling;; addn. of 40 NH4Cl to the hot filtrate, cooling, pptn.; washing with 15 ml 20 % NH4Cl in aq. NH3 and acetone; drying in vac. over P2O5;;

upstream raw materials:

ruthenium(III) chloride trihydrate

hydrazine hydrate

ammonia

hexaamineruthenium(II)

Downstream raw materials:

hexammine ruthenium(III) chloride

Ru(NH₃)6⁽³⁺⁾*3OSO₂CF₃^(1-)=(Ru(NH₃)6)(OSO₂CF₃)3

mercury(II) chloride

Refernces

• 1、 Il'in,Emel'Yanov,Baidina,Alferova,Korol'Kov. "Study of nitrosation of hexaammineruthenium(II): Crystal structure of trans-[RuNO(NH3)4Cl]Cl2". . p. 62 - 70. Retrieved 2007.
• 2、 Johnson, Craig R.,Myser, Terry K.,Shepherd, Rex E.. "Spin-trapping studies of the reduction of O2 and H2O2 by titanium(III), iron(II), and ruthenium(II) complexes". . p. 1089 - 1095. Retrieved 2008/10/08.