Bispicric acid nickel(II) salt

Base Information

• Chemical Name: Bispicric acid nickel(II) salt
• CAS No.: 63085-06-3
• Molecular Formula: C6H3N3O7.1/2Ni
• Molecular Weight: 514.886
• DSSTox Substance ID: DTXSID401333810
• Nikkaji Number: J1.363.268E
• Mol file: 63085-06-3.mol

Synonyms:Bispicric acid nickel(II) salt;63085-06-3;Picric acid, nickel(2+) salt;NIOSH/TJ7890000;DTXSID401333810;TJ78900000

Chemical Property of Bispicric acid nickel(II) salt

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 0
• Exact Mass: 513.913890
• Heavy Atom Count: 33
• Complexity: 292

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=C(C=C(C(=C1[N+](=O)[O-])[O-])[N+](=O)[O-])[N+](=O)[O-].C1=C(C=C(C(=C1[N+](=O)[O-])[O-])[N+](=O)[O-])[N+](=O)[O-].[Ni+2]

Technology Process of Bispicric acid nickel(II) salt

There total 7 articles about Bispicric acid nickel(II) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

nickel(II) chloride hexahydrate + silver picrate (146-84-9) → nickel(II) picrate (63085-06-3)

Guidance literature:

In water; byproducts: AgCl; mixed; filtered, concd., washed with C6H6 and CHCl3, recrystd. from 1:1 CH3OH:H2O, dried in vac over conc. H2SO4;

DOI:10.1081/SIM-120020332

Reference yield:

nickel(II) carbonate (719261-06-0) + 2,4,6-Trinitrophenol (88-89-1) → nickel(II) picrate (63085-06-3)

Guidance literature:

dried in vac. over phosphorous pentoxide;

Reference yield:

2,4,6-Trinitrophenol (88-89-1) → nickel(II) picrate (63085-06-3)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol; water

2: water

In methanol; water;

DOI:10.1081/SIM-120020332

upstream raw materials:

silver picrate

nickel(II) carbonate

2,4,6-Trinitrophenol

nickel dichloride

Downstream raw materials:

Ni[(NO₂)3C₆H₂(O)]2[C₇H₄NS(C₆H₄NH₂)]2

Ni[(NO₂)3C₆H₂(O)]2[C₇H₄NS(C₆H₄NH₂)]2

Ni[(NO₂)3C₆H₂(O)]2[(C₇H₅N₂)2C₅H₃N]2

Ni[(NO₂)3C₆H₂(O)]2[C₁₂H₈N₂]2