Borinic acid,B,B-dibutyl-, butyl ester

Base Information

• Chemical Name: Borinic acid,B,B-dibutyl-, butyl ester
• CAS No.: 3027-56-3
• Molecular Formula: C12H27 B O
• Molecular Weight: 198.157
• Hs Code.: 2931900090
• Mol file: 3027-56-3.mol

Synonyms:Borinicacid, dibutyl-, butyl ester (6CI,7CI,8CI,9CI); Borane, butoxydibutyl-;Butoxydibutylboron; Butyl dibutylborinate; Dibutylbutoxyborane; Super-BondC&B Catalyst

Chemical Property of Borinic acid,B,B-dibutyl-, butyl ester

Chemical Property:

• PSA: 9.23000
• LogP: 4.39480

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Borinic acid,B,B-dibutyl-, butyl ester

There total 2 articles about Borinic acid,B,B-dibutyl-, butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

morpholinodibutylborane (126215-26-7) + 1-(chloromethoxy)butane (2351-69-1) → N-(chloromethyl)morpholine (16158-87-5) + Dibutylboran-butylester (3027-56-3)

Guidance literature:

for 48h; Product distribution; Ambient temperature; var. aminoboranes; other chloromethyl alkyl ether;

Reference yield:

(di-n-butyl)cyanoborane (99066-49-6) + butan-1-ol (71-36-3) → hydrogen cyanide (74-90-8) + Dibutylboran-butylester (3027-56-3)

Guidance literature:

heating;

DOI:10.1021/ja01528a022

Reference yield: 89.0%

Dibutylboran-butylester (3027-56-3) + phosphorus pentachloride (10026-13-8,874483-75-7) → n-Butyl chloride (109-69-3) + dibutylchloroborane (1730-69-4) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

exothermic react.; removing C4H9Cl and OPCl3 at reduced pressure, distn. of residue;

upstream raw materials:

morpholinodibutylborane

1-(chloromethoxy)butane

(di-n-butyl)cyanoborane

butan-1-ol

Downstream raw materials:

(n-C₄H₉)2BNHC₆H₅

n-Butyl chloride

dibutylchloroborane

trichlorophosphate

Refernces

• 1、 Bagdasaryan, G. B.,Badalyan, K. S,Indzhikyan, M. G.. "REACTION OF AMINOBORANES WITH α-CHLORO ETHERS". . p. 1745 - 1746. Retrieved 2007/10/02.