2-Chloro-1,3,2-dioxaphosphinane

Base Information

• Chemical Name: 2-Chloro-1,3,2-dioxaphosphinane
• CAS No.: 6362-89-6
• Molecular Formula: C3H6ClO2P
• Molecular Weight: 140.506
• DSSTox Substance ID: DTXSID30503756
• Wikidata: Q82357789
• Mol file: 6362-89-6.mol

Synonyms:2-chloro-1,3,2-dioxaphosphorinane;2-Chloro-1,3,2-dioxaphosphinane;6362-89-6;SCHEMBL8495194;DTXSID30503756

Chemical Property of 2-Chloro-1,3,2-dioxaphosphinane

Chemical Property:

• Vapor Pressure: 6.522mmHg at 25°C
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 139.9793941
• Heavy Atom Count: 7
• Complexity: 54.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1COP(OC1)Cl

Technology Process of 2-Chloro-1,3,2-dioxaphosphinane

There total 3 articles about 2-Chloro-1,3,2-dioxaphosphinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

trimethyleneglycol (504-63-2) → 1,3-Dichloropropane (142-28-9) + 2-chloro-1,3,2-dioxaphosphinane (6362-89-6) + 3-chloro-n-propyl-dichlorophosphite

Guidance literature:

With phosphorus trichloride; In dichloromethane; for 2h; Ambient temperature;

Reference yield:

1-[1,3,2]Dioxaphosphinan-2-yl-pyrrolidin-2-one (176172-29-5) → N-trimethylsilyl-pyrrolidin-2-one (14468-90-7) + 2-chloro-1,3,2-dioxaphosphinane (6362-89-6)

Guidance literature:

at -6.1 - 69.9 ℃; Equilibrium constant; Thermodynamic data; δH;

DOI:10.1007/BF00696723

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1-[1,3,2]Dioxaphosphinan-2-yl-pyrrolidin-2-one (176172-29-5) → N-trimethylsilyl-pyrrolidin-2-one (14468-90-7) + 2-chloro-1,3,2-dioxaphosphinane (6362-89-6)

Guidance literature:

at -6.15 - 69.85 ℃; Equilibrium constant; Thermodynamic data;

DOI:10.1007/BF00696723

upstream raw materials:

trimethyleneglycol

1-[1,3,2]Dioxaphosphinan-2-yl-pyrrolidin-2-one

chloro-trimethyl-silane

Downstream raw materials:

2,2'-(o-phenyldioxy)-1,3,2-dioxaphosphorinane-1',3',2'-dioxaphosphorinane

2-(3,3-dimethyl-2-oxo-4-phenylazetidin-1-yl)-1,3,2-dioxaphosphorinane

chloro-trimethyl-silane

1-[1,3,2]Dioxaphosphinan-2-yl-pyrrolidin-2-one