Bis(trimethylsilyl) phenylphosphonotrithioate

Base Information

Chemical Name:Bis(trimethylsilyl) phenylphosphonotrithioate
CAS No.:63853-25-8
Molecular Formula:C₁₂H₂₃PS₃Si₂
Molecular Weight:350.657
Hs Code.:
DSSTox Substance ID:DTXSID80548117
Wikidata:Q82426722

Synonyms:Bis(trimethylsilyl) phenylphosphonotrithioate;63853-25-8;DTXSID80548117

Suppliers and Price of Bis(trimethylsilyl) phenylphosphonotrithioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bis(trimethylsilyl) phenylphosphonotrithioate

Chemical Property:

PSA：92.50000
LogP:6.40820
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:350.02380432
Heavy Atom Count:18
Complexity:294

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)SP(=S)(C1=CC=CC=C1)S[Si](C)(C)C

Technology Process of Bis(trimethylsilyl) phenylphosphonotrithioate

There total 1 articles about Bis(trimethylsilyl) phenylphosphonotrithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 63853-25-8
phenyltrithiophosphonic acid bis(trimethylsilyl) ester

Guidance literature:: Thiophosphonsaeureanhydrid (7), Hexamethyldisilylthian (4);
DOI:10.1002/zaac.19774310124

Reference yield: 58.0%

: 63853-25-8
phenyltrithiophosphonic acid bis(trimethylsilyl) ester

: 563-63-3
silver(I) acetate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: [Ag₁₂(PhS₂P-PS₂Ph)6(Ph₂P(CH₂)2P(S)Ph₂)6]

Guidance literature:: In dichloromethane; under N2; PhP(S)(SSiMe3)2 (1.44 mmol) added to soln. of silver acetate (1.44 mmol) and 1,2-bis(diphenylphosphanyl)ethane (1.44 mmol) in CH2Cl2 at -40°C; stirred for 2 h; warmed to -10°C; kept at 0°C for 2 d; concd.; heptane added; ppt. re-dissolved by shaking; kept at 0°C for more than 4 wk or at room temp. for 3 wk; elem. anal.;
DOI:10.1002/ejic.200400738

Reference yield: 52.0%

: 63853-25-8
phenyltrithiophosphonic acid bis(trimethylsilyl) ester

: 35342-67-7,35342-68-8
copper (I) tert-butoxide

: 594-09-2
trimethylphosphane

: 794516-57-7
[(C₆H₅PS₃)2Cu₄(P(CH₃)3)5]

Guidance literature:: In toluene; under N2, 1 equiv. of PMe3 was added to toluene soln. of Cu-compd., 0.5 equiv. of Si-compd. was added, stirring for 1 h; soln. was filtered, concd. to half of its original vol., crystn. at 0 °C for 3 d;
DOI:10.1002/zaac.200400049