7-Chloro-7-phenylbicyclo[4.1.0]heptane

Base Information

• Chemical Name: 7-Chloro-7-phenylbicyclo[4.1.0]heptane
• CAS No.: 13383-32-9
• Molecular Formula: C13H15 Cl
• Molecular Weight: 206.715
• NSC Number: 133260
• DSSTox Substance ID: DTXSID30299849
• Mol file: 13383-32-9.mol

Synonyms:13383-32-9;7-chloro-7-phenylbicyclo[4.1.0]heptane;NSC133260;7-phenyl-7-chloronorcarane;DTXSID30299849;NSC-133260

Chemical Property of 7-Chloro-7-phenylbicyclo[4.1.0]heptane

Chemical Property:

• Vapor Pressure: 0.00279mmHg at 25°C
• Boiling Point: 294.8°Cat760mmHg
• Flash Point: 120.1°C
• Density: 1.14g/cm³
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 206.0862282
• Heavy Atom Count: 14
• Complexity: 205

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC2C(C1)C2(C3=CC=CC=C3)Cl

Technology Process of 7-Chloro-7-phenylbicyclo[4.1.0]heptane

There total 6 articles about 7-Chloro-7-phenylbicyclo[4.1.0]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Benzotrichlorid (98-07-7) + cyclohexene (110-83-8) → (E)-1,2-diphenyl-ethene (103-30-0) + 7t(und c)-Chlor-7c(und t)-phenyl-(1rH.6cH)-norcaran (13383-32-9) + (E)-1,2-dichlorostilbene (951-86-0) + diphenyl acetylene (501-65-5)

Guidance literature:

With magnesium; In tetrahydrofuran; for 3h; Product distribution; Ambient temperature; other benzotrihalides; other olefins;

DOI:10.1016/0022-328X(90)85094-F

Reference yield:

benzylidene dichloride (98-87-3) + cyclohexene (110-83-8) → 7t(und c)-Chlor-7c(und t)-phenyl-(1rH.6cH)-norcaran (13383-32-9)

Guidance literature:

With sodium t-butanolate;

DOI:10.1021/ja01073a034

Reference yield:

phenylchloropyridinium ylide (115732-59-7) + cyclohexene (110-83-8) → 7t(und c)-Chlor-7c(und t)-phenyl-(1rH.6cH)-norcaran (13383-32-9)

Guidance literature:

In pentane; at 9.84 ℃; Further Variations:; Temperatures; Kinetics;

DOI:10.1021/ja8005226

upstream raw materials:

dimethyl phenylboronate

phenyl(bromodichloromethyl)mercury

cyclohexene

Benzotrichlorid

Downstream raw materials:

exo-7-phenyl-norcarane