Silane, (1,1-dimethylethyl)[[2-fluoro-5,5-bis(phenylmethoxy)pentyl]oxy]diphenyl-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)[[2-fluoro-5,5-bis(phenylmethoxy)pentyl]oxy]diphenyl-
CAS No.:645413-06-5
Molecular Formula:C35H41FO3Si
Molecular Weight:556.793
Hs Code.:

Synonyms:

Suppliers and Price of Silane, (1,1-dimethylethyl)[[2-fluoro-5,5-bis(phenylmethoxy)pentyl]oxy]diphenyl-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, (1,1-dimethylethyl)[[2-fluoro-5,5-bis(phenylmethoxy)pentyl]oxy]diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Silane, (1,1-dimethylethyl)[[2-fluoro-5,5-bis(phenylmethoxy)pentyl]oxy]diphenyl-

There total 4 articles about Silane, (1,1-dimethylethyl)[[2-fluoro-5,5-bis(phenylmethoxy)pentyl]oxy]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3885-22-1
ethyl-2-fluoro-4-pentenoate

: 645413-06-5
5-(tert-butyldiphenylsilyloxy)-4-fluoropentanaldibenzylacetal

Guidance literature:: Multi-step reaction with 5 steps

1.1: LiAlH₄ / diethyl ether / 18 h / 23 °C

2.1: 13.17 g / imidazole / dimethylformamide / 12 h

3.1: BH₃*SMe₂ / tetrahydrofuran / 72 h / 23 °C

3.2: 83 percent / aq. H₂O₂; NaOH / tetrahydrofuran / 48 h / 23 °C

4.1: 95 percent / Dess-Martin periodinane / CH₂Cl₂ / 16 h

5.1: 86 percent / p-toluenesulfonic acid monohydrate / benzene / 20 h / 80 °C

With 1H-imidazole; lithium aluminium tetrahydride; dimethylsulfide borane complex; Dess-Martin periodane; toluene-4-sulfonic acid; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; benzene; 4.1: Dess-Martin oxidation;
DOI:10.1021/ja037935a

Reference yield:

: 2-fluoro-4-penten-1-ol

: 645413-06-5
5-(tert-butyldiphenylsilyloxy)-4-fluoropentanaldibenzylacetal

Guidance literature:: Multi-step reaction with 4 steps

1.1: 13.17 g / imidazole / dimethylformamide / 12 h

2.1: BH₃*SMe₂ / tetrahydrofuran / 72 h / 23 °C

2.2: 83 percent / aq. H₂O₂; NaOH / tetrahydrofuran / 48 h / 23 °C

3.1: 95 percent / Dess-Martin periodinane / CH₂Cl₂ / 16 h

4.1: 86 percent / p-toluenesulfonic acid monohydrate / benzene / 20 h / 80 °C

With 1H-imidazole; dimethylsulfide borane complex; Dess-Martin periodane; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; benzene; 3.1: Dess-Martin oxidation;
DOI:10.1021/ja037935a

Reference yield:

: 645413-03-2
1-(tert-butyldiphenylsilyloxy)-2-fluoropent-4-ene

: 645413-06-5
5-(tert-butyldiphenylsilyloxy)-4-fluoropentanaldibenzylacetal

Guidance literature:: Multi-step reaction with 3 steps

1.1: BH₃*SMe₂ / tetrahydrofuran / 72 h / 23 °C

1.2: 83 percent / aq. H₂O₂; NaOH / tetrahydrofuran / 48 h / 23 °C

2.1: 95 percent / Dess-Martin periodinane / CH₂Cl₂ / 16 h

3.1: 86 percent / p-toluenesulfonic acid monohydrate / benzene / 20 h / 80 °C

With dimethylsulfide borane complex; Dess-Martin periodane; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; benzene; 2.1: Dess-Martin oxidation;
DOI:10.1021/ja037935a