Gold, chloro(N-cyclohexylcyclohexanamine)-

Base Information

• Chemical Name: Gold, chloro(N-cyclohexylcyclohexanamine)-
• CAS No.: 64704-71-8
• Molecular Formula: C12H23AuClN
• Molecular Weight: 413.741
• Mol file: 64704-71-8.mol

Synonyms:

Chemical Property of Gold, chloro(N-cyclohexylcyclohexanamine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Gold, chloro(N-cyclohexylcyclohexanamine)-

There total 1 articles about Gold, chloro(N-cyclohexylcyclohexanamine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + N-cyclohexyl-cyclohexanamine (101-83-7) → chloro(dicyclohexylamine)gold(I) (64704-71-8)

Guidance literature:

In neat (no solvent); stirring (exclusion of light, room temperature, 1 h); pptn. (light petroleum ether, -18°C, 1 h), filtration, recrystn. (CH2Cl2/light petroleum ether); elem. anal.;

DOI:10.1002/(sici)1099-0682(199907)1999:7<1103::aid-ejic1103>3.0.co;2-0

Reference yield: 91.0%

silver(I) hexafluorophosphate (26042-63-7) + chloro(dicyclohexylamine)gold(I) (64704-71-8) + triphenylphosphine sulfide (3878-45-3) → Au(P(C6H5)3S)2(1+)*PF6(1-)=[Au(P(C6H5)3S)2]PF6 (64736-29-4)

Guidance literature:

In dichloromethane; byproducts: AgCl; stoich. amts. of Au-complex and ligand, 10 % excess of AgPF6; filtration off of AgCl, concn. (vac.), crystn. on Et2O addn. (refrigerator); elem. anal.;

DOI:10.1039/DT9770001434

Reference yield: 59.0%

silver hexafluoroantimonate (26042-64-8) + chloro(dicyclohexylamine)gold(I) (64704-71-8) + N-cyclohexyl-cyclohexanamine (101-83-7) → bis(dicyclohexylamine)gold(I) hexafluoroantimonate

Guidance literature:

In dichloromethane; byproducts: AgCl; stirring (exclusion of light, room temperature, 1 h); filtration from AgCl through layer of MgSO4, pptn. (light petroleum ether, -18°C, overnight); elem. anal.;

DOI:10.1002/(sici)1099-0682(199907)1999:7<1103::aid-ejic1103>3.0.co;2-0

upstream raw materials:

(tetrahydrothiophene)gold(I) chloride

N-cyclohexyl-cyclohexanamine

Downstream raw materials:

Au(P(C₆H₅)3S)2⁽¹⁺⁾*PF₆^(1-)=[Au(P(C₆H₅)3S)2]PF₆