Ethenyl(difluoro)phenylsilane

Base Information

• Chemical Name: Ethenyl(difluoro)phenylsilane
• CAS No.: 651-01-4
• Molecular Formula: C8H8F2Si
• Molecular Weight: 170.234
• DSSTox Substance ID: DTXSID60566531
• Nikkaji Number: J483.842D
• Wikidata: Q82452183
• Mol file: 651-01-4.mol

Synonyms:Ethenyl(difluoro)phenylsilane;651-01-4;SCHEMBL15302071;DTXSID60566531

Chemical Property of Ethenyl(difluoro)phenylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 170.03633311
• Heavy Atom Count: 11
• Complexity: 139

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C[Si](C1=CC=CC=C1)(F)F

Technology Process of Ethenyl(difluoro)phenylsilane

There total 1 articles about Ethenyl(difluoro)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenylvinyldichlorosilane (7719-02-0) → difluorophenylvinylsilane (651-01-4)

Guidance literature:

With antimony(III) fluoride;

DOI:10.1007/BF00920292

Reference yield: 80.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + difluorophenylvinylsilane (651-01-4) → Difluoro-phenyl-((E)-styryl)-silane

Guidance literature:

Grubbs catalyst first generation; In dichloromethane; for 20h; Heating;

DOI:10.1016/j.jorganchem.2005.07.091

Reference yield: 44.0%

ethanol (64-17-5) + carbon monoxide (201230-82-2) + difluorophenylvinylsilane (651-01-4) → Ethyl 3-(difluorophenylsilyl)propionate (137787-43-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; In benzene; at 120 ℃; under 44130.5 Torr;

DOI:10.1039/c39910001247

upstream raw materials:

phenylvinyldichlorosilane

Downstream raw materials:

Ethyl 3-(difluorophenylsilyl)propionate