Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl-

Base Information

Chemical Name:Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl-
CAS No.:651022-13-8
Molecular Formula:C48H37P3
Molecular Weight:706.743
Hs Code.:
DSSTox Substance ID:DTXSID60475134
Nikkaji Number:J1.978.738I
Wikidata:Q82305419

Synonyms:Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl-;651022-13-8;SCHEMBL1768448;DTXSID60475134;2,2',6-Tris(diphenylphosphino)biphenyl

Suppliers and Price of Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl-

Chemical Property:

XLogP3:11.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:10
Exact Mass:706.21081217
Heavy Atom Count:51
Complexity:875

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6P(C7=CC=CC=C7)C8=CC=CC=C8

Technology Process of Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl-

There total 1 articles about Phosphine, [1,1'-biphenyl]-2,2',6-triyltris[diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1300117-89-8
2-bromo-2′,6-diiodo-1,1′-biphenyl

: 829-85-6
diphenylphosphane

: 651022-13-8
biphenyl-2,2',6-triyltris(diphenylphosphine)

Guidance literature:: With potassium acetate; palladium diacetate; In N,N-dimethyl acetamide; at 130 ℃; for 3h; Inert atmosphere;
DOI:10.1002/chem.201101529

Reference yield: 99.0%

: 37366-09-9
dichloro(benzene)ruthenium(II) dimer

: 439090-23-0,312969-46-3,360779-01-7
(S)-3,3'-dimethyl-2,2'-diamino-1,1'-binaphthyl

: 651022-13-8
biphenyl-2,2',6-triyltris(diphenylphosphine)

: 651022-12-7
((S)-2,6,2'-tris(diphenylphosphanyl)biphenyl)((S)-3,3'-dimethyl-2,2'-diamino-1,1'-binaphthyl)RuCl₂

Guidance literature:: In N,N-dimethyl-formamide; DMF addded to mixt. of Ru-complex and diphosphine under Ar, stirred at 100 °C for 3 h; soln. obtained concd. at 50 °C under reduced pressure, C2H4Cl2 added to mixt. of complex obtained and diamine underAr, stirred at 80 °C for 2 h; soln. concd. under reduced pressure;
DOI:10.1002/anie.200352277