Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl-

Base Information

Chemical Name:Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl-
CAS No.:651033-72-6
Molecular Formula:C22H28OSi
Molecular Weight:336.549
Hs Code.:
DSSTox Substance ID:DTXSID80471532
Nikkaji Number:J1.983.907I

Synonyms:Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl-;651033-72-6;DTXSID80471532

Suppliers and Price of Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:9
Exact Mass:336.190942047
Heavy Atom Count:24
Complexity:373

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCO[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(CCC(=C)C)C=C

Technology Process of Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl-

There total 1 articles about Silane, (1-ethenyl-4-methyl-4-pentenyl)ethoxydiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 64-17-5
ethanol

: 33935-31-8
chloro(N,N-diethylamino)diphenylsilane

: 152063-05-3
(E)-7-chloro-2-methylhepta-1,5-diene

: 651033-72-6
ethoxy-(4-methyl-1-vinyl-pent-4-enyl)-diphenyl-silane

: Ethoxy-((E)-6-methyl-hepta-2,6-dienyl)-diphenyl-silane

Guidance literature:: chloro(N,N-diethylamino)diphenylsilane; With lithium; In tetrahydrofuran; at 0 ℃;

In tetrahydrofuran; at 0 ℃;

ethanol; (E)-7-chloro-2-methylhepta-1,5-diene; In tetrahydrofuran; at -78 - 20 ℃; Further stages.;
DOI:10.1039/b309848f

Reference yield: 65.0%

: 183592-10-1
(E)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-but-2-enal

: 563-47-3
3-Chloro-2-methylpropene

: 651033-72-6
ethoxy-(4-methyl-1-vinyl-pent-4-enyl)-diphenyl-silane

: (2E,6E)-1-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,3R)-3-(ethoxy-diphenyl-silanyl)-2-iodomethyl-1-methyl-cyclopentyl]-2,6-dimethyl-octa-2,6-dien-4-ol

Guidance literature:: Multistep reaction.;
DOI:10.1039/b309848f

Reference yield:

: 651033-72-6
ethoxy-(4-methyl-1-vinyl-pent-4-enyl)-diphenyl-silane

: (5E,9E)-(1R,12aR)-12-Benzenesulfonyl-8-benzyloxymethoxy-3a,6,10-trimethyl-1,2,3,3a,4,7,8,11,12,12a-decahydro-cyclopentacycloundecen-1-ol

Guidance literature:: Multi-step reaction with 7 steps

1: 78 percent / hexamethylphosphoric acid triamide; diethyl ether / 2 h / 45 °C

2: 83 percent / i-PrEt₂N / CH₂Cl₂ / 0 - 20 °C

3: TBAF / tetrahydrofuran / 1 h / 20 °C

4: H₂O₂; KHCO₃ / methanol; tetrahydrofuran / 12 h

5: 94 percent / N-chlorosuccinimide; Me₂S / CH₂Cl₂ / -20 - 0 °C

6: 78 percent / LiHMDS / tetrahydrofuran / 5 h / Heating

With N-chloro-succinimide; dimethylsulfide; N,N-diethyl-N-isopropylamine; tetrabutyl ammonium fluoride; dihydrogen peroxide; potassium hydrogencarbonate; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; dichloromethane; 5: Tamao oxidation;
DOI:10.1039/b309848f