Benzene,1,1'-selenobis[4-methoxy-

Base Information

• Chemical Name: Benzene,1,1'-selenobis[4-methoxy-
• CAS No.: 22216-66-6
• Molecular Formula: C14H14 O2 Se
• Molecular Weight: 293.224
• Mol file: 22216-66-6.mol

Synonyms:Anisole,4,4'-selenodi- (6CI,8CI); 1,1'-Selenobis[4-methoxybenzene];Bis(4-methoxyphenyl) selenide; Bis(p-methoxyphenyl) selenide;Di(p-methoxyphenyl) selenide; Di-4-anisyl selenide; Di-p-anisyl selenide; NSC632602

Chemical Property of Benzene,1,1'-selenobis[4-methoxy-

Chemical Property:

• Boiling Point: 376.3°Cat760mmHg
• Flash Point: 181.4°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene,1,1'-selenobis[4-methoxy-

There total 31 articles about Benzene,1,1'-selenobis[4-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

bis(4-methoxyphenyl)diselenide (38762-70-8) + 4-methoxyphenylboronic acid (5720-07-0) → bis(4-methoxyphenyl)selenide (22216-66-6)

Guidance literature:

With Oxone; In ethanol; at 60 ℃; for 6h; Schlenk technique;

DOI:10.1055/s-0036-1591992

Reference yield: 96.0%

para-iodoanisole (696-62-8) → bis(4-methoxyphenyl)selenide (22216-66-6)

Guidance literature:

With potassium selenocyanate; potassium hydroxide; In dimethyl sulfoxide; at 110 ℃; for 15h;

DOI:10.1055/s-0030-1260553

Reference yield: 95.0%

selenourea (630-10-4) + para-iodoanisole (696-62-8) → bis(4-methoxyphenyl)selenide (22216-66-6)

Guidance literature:

With copper(II) oxide; potassium hydroxide; In dimethyl sulfoxide; at 80 ℃; for 10h;

DOI:10.1021/jo102017g

upstream raw materials:

di(p-anisyl)selenium(IV) chloride

methoxybenzene

4-(4-hydroxyphenylselanyl)phenol

methyl iodide

Downstream raw materials:

bis(p-methoxyphenyl) selenone

selenium

bis(4-methoxyphenyl)diselenide

methoxybenzene

Refernces

• 1、 Cai, Hu,Fu, Zhengjiang,Guo, Shengmei,He, Dongdong,Yi, Xuezheng,Yin, Jian. "An electrochemical method for deborylative selenylation of arylboronic acids under metal- and oxidant-free conditions". supporting information. p. 130 - 135. Retrieved 2022/01/19.
• 2、 Zhu, Zechen,Luo, Jie,Zhao, Xiaodan. "Combination of Lewis Basic Selenium Catalysis and Redox Selenium Chemistry: Synthesis of Trifluoromethylthiolated Tertiary Alcohols with Alkenes". supporting information. p. 4940 - 4943. Retrieved 2017/09/23.