Methyl 7-chloronaphthalene-1-carboxylate

Base Information

Chemical Name:Methyl 7-chloronaphthalene-1-carboxylate
CAS No.:5471-31-8
Molecular Formula:C₁₂H₉ClO₂
Molecular Weight:220.655
Hs Code.:2916399090
NSC Number:26059
DSSTox Substance ID:DTXSID30282473
Wikidata:Q82016758
Mol file:5471-31-8.mol

Synonyms:methyl 7-chloronaphthalene-1-carboxylate;5471-31-8;Methyl 7-chloro-1-naphthoate;NSC26059;7-Chloro-naphthalene-1-carboxylic acid methyl ester;SCHEMBL3571702;DTXSID30282473;NSC 26059;NSC-26059

Suppliers and Price of Methyl 7-chloronaphthalene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alichem
Methyl7-chloronaphthalene-1-carboxylate
1g
$ 1634.45

Alichem
Methyl7-chloronaphthalene-1-carboxylate
500mg
$ 1068.20

Total 5 raw suppliers

Chemical Property of Methyl 7-chloronaphthalene-1-carboxylate

Chemical Property:

Vapor Pressure:0.000105mmHg at 25°C
Boiling Point:337.4°Cat760mmHg
Flash Point:173.7°C
PSA：26.30000
Density:1.272g/cm³
LogP:3.27980
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:220.0291072
Heavy Atom Count:15
Complexity:242

Purity/Quality:

99% ^*data from raw suppliers

Methyl7-chloronaphthalene-1-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=CC2=C1C=C(C=C2)Cl

Technology Process of Methyl 7-chloronaphthalene-1-carboxylate

There total 5 articles about Methyl 7-chloronaphthalene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.9%

: 67-56-1
methanol

: 58926-30-0
7-chloronaphthalene-1-carboxylic acid

: 5471-31-8
methyl 7-chloro-1-naphthoate

Guidance literature:: With sulfuric acid; at 80 ℃; for 15h;

Reference yield:

: 91-58-7
2-chloronaphthalene

: 5471-31-8
methyl 7-chloro-1-naphthoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: aluminum (III) chloride / dichloromethane / 2 h / 0 °C / Inert atmosphere

1.2: 2 h / 3 °C

2.1: sodium hypochlorite / ethanol / 15 h / 28 °C

3.1: sulfuric acid / 15 h / 80 °C

With aluminum (III) chloride; sodium hypochlorite; sulfuric acid; In ethanol; dichloromethane;

Reference yield:

: 58149-93-2
1-(7-chloronaphthalen-1-yl)ethan-1-one

: 5471-31-8
methyl 7-chloro-1-naphthoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hypochlorite / ethanol / 15 h / 28 °C

2: sulfuric acid / 15 h / 80 °C

With sodium hypochlorite; sulfuric acid; In ethanol;