Germane, iodotris(trifluoromethyl)-

Base Information

• Chemical Name: Germane, iodotris(trifluoromethyl)-
• CAS No.: 66348-18-3
• Molecular Formula: C3F9GeI
• Molecular Weight: 406.56200
• European Community (EC) Number: 621-814-8
• DSSTox Substance ID: DTXSID80403939
• Nikkaji Number: J1.410.575A
• Wikidata: Q82207848
• Mol file: 66348-18-3.mol

Synonyms:Germane, iodotris(trifluoromethyl)-;66348-18-3;Iodo-tris(trifluoromethyl)germane;TRIS(TRIFLUOROMETHYL)IODOGERMANE;iodotris(trifluoromethyl)germane;SCHEMBL4658635;DTXSID80403939;SNDJUKPGRATGFE-UHFFFAOYSA-N;tris(trifluoromethyl)germanium(iv) iodide

Chemical Property of Germane, iodotris(trifluoromethyl)-

Chemical Property:

• Vapor Pressure: 115 mm Hg ( 20 °C)
• Melting Point: -40oC(lit.)
• Refractive Index: n20/D 1.351(lit.)
• Boiling Point: 72oC(lit.)
• Flash Point: 8.6oC
• PSA: 0.00000
• Density: 2.074 g/mL at 25oC(lit.)
• LogP: 4.93110
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 407.81128
• Heavy Atom Count: 14
• Complexity: 174

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)[Ge](C(F)(F)F)(C(F)(F)F)I

Technology Process of Germane, iodotris(trifluoromethyl)-

There total 6 articles about Germane, iodotris(trifluoromethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

germanium tetraiodide (13450-95-8) + bis(trifluoromethyl)mercury (371-76-6) → tris(trifluoromethyl)germyl iodide (66348-18-3) + tetrakis(trifluoromethyl)germane (55642-43-8)

Guidance literature:

120°C, 120 h; in sealed tube; molar ratio based on GeI4: 1.72;

DOI:10.1021/ja00474a013

Reference yield: 72.0%

germanium tetraiodide (13450-95-8) + bis(trifluoromethyl)mercury (371-76-6) → tris(trifluoromethyl)fluorogermane (66348-16-1) + tris(trifluoromethyl)germyl iodide (66348-18-3) + tetrakis(trifluoromethyl)germane (55642-43-8)

Guidance literature:

120°C, 120 h; in sealed tube; molar ratio based on GeI4: 2.0;

DOI:10.1021/ja00474a013

Reference yield: 53.0%

germanium tetraiodide (13450-95-8) + bis(trifluoromethyl)mercury (371-76-6) → perfluormethylgermanium iodide (1512-08-9) + perfluormethylgermanium iodide (754-36-9) + tris(trifluoromethyl)germyl iodide (66348-18-3)

Guidance literature:

120°C, 120 h; in sealed tube; molar ratio based on GeI4: 0.98;

DOI:10.1021/ja00474a013

upstream raw materials:

germanium tetraiodide

bis(trifluoromethyl)mercury

Downstream raw materials:

Methyl-tris-trifluoromethyl-germane

bistris(trifluoromethyl)germyl telluride

lithium iodide

perfluormethylgermanium iodide