Tris(trifluoromethyl)chlorogermane

Base Information

• Chemical Name: Tris(trifluoromethyl)chlorogermane
• CAS No.: 66348-17-2
• Molecular Formula: C3ClF9Ge
• Molecular Weight: 315.062
• Mol file: 66348-17-2.mol

Synonyms:

Chemical Property of Tris(trifluoromethyl)chlorogermane

Chemical Property:

• Vapor Pressure: 1040mmHg at 25°C
• Boiling Point: 16°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 4.73490

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tris(trifluoromethyl)chlorogermane

There total 4 articles about Tris(trifluoromethyl)chlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis{tris(trifluoromethyl)germyl}mercury (82477-25-6) + mercury dichloride → bis(trifluoromethyl)germanium chloride (66348-17-2) + mercury

Guidance literature:

In tetrahydrofuran; dry oxygen-free solvents; sealing mixt. of Ge-compd. in THF and HgCl2 in glass ampoule, heating to 100°C (5 h); Ge(CF3)3Cl not isolated; detn. by (19)F-NMR spectroscopy;

Reference yield: 92.0%

tris(trifluoromethyl)germyl iodide (66348-18-3) → bis(trifluoromethyl)germanium chloride (66348-17-2)

Guidance literature:

With silver(I) chloride; 20°C, 24 h; excess of AgCl;

DOI:10.1021/ja00474a013

Reference yield:

bis{tris(trifluoromethyl)germyl}mercury (82477-25-6) → tris(trifluoromethyl)germane (66348-14-9) + bis(trifluoromethyl)germanium chloride (66348-17-2) + mercury

Guidance literature:

With hydrogenchloride; In benzene; dry oxygen-free solvents; sealing mixt. of Ge-compd. in benzene and HCl in glass ampoule, heating to 100°C (5 h); (CF3)3GeCl and (CF3)3GeH not isolated; detn. by (19)F-NMR spectroscopy;

upstream raw materials:

tris(trifluoromethyl)germyl iodide

bis{tris(trifluoromethyl)germyl}mercury

Downstream raw materials:

bistris(trifluoromethyl)germyl telluride

tert-butyldimethylsilyl chloride