(Z)-Tri-n-butyl(1-propenyl)tin

Base Information

Chemical Name:(Z)-Tri-n-butyl(1-propenyl)tin
CAS No.:66680-84-0
Molecular Formula:C₁₅H₃₂Sn
Molecular Weight:331.129
Hs Code.:
European Community (EC) Number:677-902-1,677-906-3

Synonyms:(Z)-Tri-n-butyl(1-propenyl)tin;66680-84-0;(Z)-Tributyl(prop-1-en-1-yl)stannane;CIS-TRI-N-BUTYL(1-PROPENYL)TIN;Tri-n-butyl(1-propenyl)tin, cis + trans;tri-n-butylpropenyltin;tributyl(1Z)-prop-1-en-1-ylstannane;tributyl-propenyl-stannane;tributyl(1-propenyl) tin;cis-2-Methylvinyltributyltin;Z-1-propenyltributyl stannane;(E)-tributyl(1-propenyl)tin;tributyl(prop-1-enyl)stannane;Z-1-propenyl tri-n-butylstannane;Z-1-propenyl-tri-n-butylstannane;cis-1-Propenyltri-n-butylstannane;cis-Tri->N-butyl(1-propenyl)tin;FJXYMVBFBYAWDR-UHFFFAOYSA-N;(E)-tributyl(prop-1-enyl)stannane;(Z)-tributyl(prop-1-enyl)stannane;105494-65-3;MFCD03425868;tributyl-[(Z)-prop-1-enyl]stannane;AKOS015843022;(E)-tributyl(prop-1-en-1-yl)stannane;(Z)-tributyl(prop-1-en-1-yl) stannane;(Z)-tributyl (prop-1-en-1-yl) stannane;cis-Tri-N-butyl(1-propenyl)tin, AldrichCPR;CS-0106370;D76643

Suppliers and Price of (Z)-Tri-n-butyl(1-propenyl)tin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
(Z)-Tri-n-butyl(1-propenyl)tin 90%
1g
$ 227.00

Matrix Scientific
(Z)-Tri-n-butyl(1-propenyl)tin 90%
5g
$ 643.00

American Custom Chemicals Corporation
(Z)-TRI-N-BUTYL(1-PROPENYL)TIN 95.00%
5MG
$ 499.72

AK Scientific
(Z)-Tri-n-butyl(1-propenyl)tin
5g
$ 918.00

Total 10 raw suppliers

Chemical Property of (Z)-Tri-n-butyl(1-propenyl)tin

Chemical Property:

Vapor Pressure:0.001mmHg at 25°C
Boiling Point:77-78oC/0.25mm
Flash Point:77-78°C/0.25mm
PSA：0.00000
LogP:5.95080
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:10
Exact Mass:332.152604
Heavy Atom Count:16
Complexity:151

Purity/Quality:

99% ^*data from raw suppliers

(Z)-Tri-n-butyl(1-propenyl)tin 90% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 26/27/28-50/53
Safety Statements: 26-27/28-45-60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C=CC
Isomeric SMILES:CCCC[Sn](CCCC)(CCCC)/C=C\C

Technology Process of (Z)-Tri-n-butyl(1-propenyl)tin

There total 8 articles about (Z)-Tri-n-butyl(1-propenyl)tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 4226-01-1
tri-n-butyltin lithium

: copper(l) cyanide

: 74-86-2,25067-58-7
acetylene

: 66680-84-0,66680-85-1,105494-65-3
(Z)-1-propenyltributyltin

Guidance literature:: With methyllithium; methyl iodide; In tetrahydrofuran; diethyl ether; at -20°C addn. of MeLi in Et2O to Bu3SnLi in THF, addn. of this mixt. to a suspn. of CuCN in THF, stirring for 15 min, cooling to -78°C, addn. of acetylene, after 30 min addn. of electrophile, after 15 to 30 min. warming to 0°C; after 1 h quenching of mixt. with NH4Cl;
DOI:10.1039/c39920000351

Reference yield: 98.0%

: 4226-01-1
tri-n-butyltin lithium

: 917-54-4
methyllithium

: copper(l) cyanide

: 74-86-2,25067-58-7
acetylene

: 74-88-4
methyl iodide

: 66680-84-0,66680-85-1,105494-65-3
(Z)-1-propenyltributyltin

Guidance literature:: In tetrahydrofuran; hexane; a soln. of stannyllithium in THF and MeLi in hexane and CuCN is stirred at -78°C for 30 min, dropwise addn. of acetylene and MeI in THF, the mixt. is stirred at this temp. for 1 h and then at 0°C for 3 h (under nitrogen); saturated aq. NH4Cl is added, extn. with Et2O, drying (MgSO4) and chromy., elem. anal.;

Reference yield: 61.0%

: 937-63-3
p-Tolyl chlorothionoformate

: 116064-59-6,117438-45-6,140150-31-8
1-tributylstannyl-propan-1-ol

: 105494-65-3,66680-85-1,66680-84-0
(E)-propenyl-tri-n-butylstannane

Guidance literature:: With sodium hydrogen sulfate; sulfuric acid; water; In pyridine; dichloromethane; byproducts: p-H3CC6H4OH; slow addn. of soln. of CH3PhOC(S)Cl in CH2Cl2 to cold (-20°C) soln. of alcohol in pyridine, 3h/0°C, ice, extd. with CH2Cl2, treatment with H2SO4 (10%), NaHCO3 (10%), H2O; mixt. warmed up to 200°C, then thermolysis at 800°C; in N2, condensation of products in a dewar vessel (liquid N2), warmed up to ambient temp.; first reaction detected by HPLC and IR, purifn. of educt by chromy. (Florisil, pentane), purifn. detected by HPLC or GC, ratio of isomers: cis/trans = 42/58;
DOI:10.1016/0022-328X(87)80020-7