Methyl 4-(acetyloxy)but-2-ynoate

Base Information

Chemical Name:Methyl 4-(acetyloxy)but-2-ynoate
CAS No.:68691-05-4
Molecular Formula:C7H8O4
Molecular Weight:156.138
Hs Code.:
DSSTox Substance ID:DTXSID00566838
Nikkaji Number:J1.834.420C
Wikidata:Q82452600

Synonyms:68691-05-4;METHYL 4-(ACETYLOXY)BUT-2-YNOATE;DTXSID00566838

Suppliers and Price of Methyl 4-(acetyloxy)but-2-ynoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Methyl 4-(acetyloxy)but-2-ynoate

Chemical Property:

XLogP3:0.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:156.04225873
Heavy Atom Count:11
Complexity:217

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)OCC#CC(=O)OC

Technology Process of Methyl 4-(acetyloxy)but-2-ynoate

There total 1 articles about Methyl 4-(acetyloxy)but-2-ynoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: 607-81-8
diethyl 2-benzylmalonate

: 23326-27-4
Methyl 2-butynoate

: 68691-05-4
methyl 4-acetoxybut-2-ynoate

: 141344-99-2
2-Methyl-4H-naphthalene-1,3,3-tricarboxylic acid diethyl ester methyl ester

: 2,2,3,3-tetrakis(ethoxycarbonyl)-1,4-diphenylbutane

Guidance literature:: With manganese triacetate; In acetic acid; at 70 ℃; for 24h;
DOI:10.1021/jo00041a034

Reference yield: 97.0%

: 68691-05-4
methyl 4-acetoxybut-2-ynoate

: 383911-55-5
3,3-dimethyl-1-butynyl p-tolyl sulfoxide

: methyl (E)-4-acetoxy-3-(p-tolylsulfinyl)-2-butenoate

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; diethylzinc; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 4.25h;
DOI:10.1021/jo034108j