Benzene, 1,1'-(1-butene-1,4-diyl)bis-, (Z)-

Base Information

• Chemical Name: Benzene, 1,1'-(1-butene-1,4-diyl)bis-, (Z)-
• CAS No.: 70388-65-7
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• DSSTox Substance ID: DTXSID10880633
• Nikkaji Number: J142.905A
• Wikidata: Q82861968
• Mol file: 70388-65-7.mol

Synonyms:Benzene, 1,1'-(1-butene-1,4-diyl)bis-, (Z)-;70388-65-7;(Z)-1,4-Diphenyl-1-butene;DTXSID10880633;NJJOGKAVAWZLAU-QPEQYQDCSA-N;[(3Z)-4-Phenyl-3-butenyl]benzene #

Chemical Property of Benzene, 1,1'-(1-butene-1,4-diyl)bis-, (Z)-

Chemical Property:

• Melting Point: 36-38 °C(Solv: hexane (110-54-3))
• Boiling Point: 145-148 °C(Press: 13 Torr)
• PSA: 0.00000
• Density: 1.0172 g/cm3
• LogP: 4.33260
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 208.125200510
• Heavy Atom Count: 16
• Complexity: 192

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CCC=CC2=CC=CC=C2
• Isomeric SMILES: C1=CC=C(C=C1)CC/C=C\C2=CC=CC=C2

Technology Process of Benzene, 1,1'-(1-butene-1,4-diyl)bis-, (Z)-

There total 97 articles about Benzene, 1,1'-(1-butene-1,4-diyl)bis-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

trans,trans-1,4-Diphenyl-1,3-butadiene (886-65-7,538-81-8) → 1-phenyl-1,2,3,4-tetrahydronaphthalene (3018-20-0) + 2-phenylethylstyrene (14213-84-4,27066-35-9,70388-65-7) + 1,4-diphenylbut-2-ene (13657-49-3)

Guidance literature:

trans,trans-1,4-Diphenyl-1,3-butadiene; With lithium vanadium(I) dihydride; In tetrahydrofuran; at 25 ℃; for 12h; Inert atmosphere;

With hydrogenchloride; In water;

DOI:10.1002/ejoc.200800461

Reference yield: 53.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → (E)-1,4-diphenylbut-1-ene (27066-35-9) + (Z)-1,4-diphenyl-1-butene (70388-65-7)

Guidance literature:

With octanol; [Ru(η⁶-cot)(η²-dmfm)2]; In 1,3,5-trimethyl-benzene; at 80 ℃; for 24h; under 30402 Torr;

DOI:10.1002/anie.200701583

Reference yield: 48.0%

trans,trans-1,4-Diphenyl-1,3-butadiene (886-65-7,538-81-8) → 1,4-diphenylbutane (1083-56-3) + 2-phenylethylstyrene (14213-84-4,27066-35-9,70388-65-7) + 1,4-diphenylbutylphosphinic acid + C16H19P

Guidance literature:

With potassium hydroxide semihydrate; phosphorus; water; In dimethyl sulfoxide; at 120 ℃; for 3h;

DOI:10.1016/j.mencom.2017.03.009

upstream raw materials:

1,4-diphenyl-1-butanol

3-phenylpropylmagnesium bromide

benzaldehyde

phenylacetylene

Downstream raw materials:

1,4-diphenylbutane

1-Phenyl-1,2,3,4-tetrahydro-naphthalene-2-sulfonic acid

styrene

1,1'-(1,2-ethanediyl)bisbenzene