1-methoxy-4-(1,2,2-triphenylethenyl)Benzene

Base Information

• Chemical Name: 1-methoxy-4-(1,2,2-triphenylethenyl)Benzene
• CAS No.: 70592-05-1
• Molecular Formula: C27H22O
• Molecular Weight: 362.471
• DSSTox Substance ID: DTXSID90461782
• Nikkaji Number: J1.904.130A
• Mol file: 70592-05-1.mol

Synonyms:Methyl-[4-(triphenyl-vinyl)-phenyl]-aether;1,1,2-triphenyl-2-(p-methoxyphenyl)ethylene;1-(4-methoxyphenyl)-1,2,2-triphenylethylene;1-methoxy-4-(triphenylethenyl)-benzene;4-triphenylvinyl-anisole;Benzene,1-methoxy-4-(triphenylethenyl);1-p-anisyl-1,2,2-triphenylethene;

Chemical Property of 1-methoxy-4-(1,2,2-triphenylethenyl)Benzene

Chemical Property:

• Melting Point: 131-132 °C
• Boiling Point: 461.0±14.0 °C(Predicted)
• PSA: 9.23000
• Density: 1.099±0.06 g/cm3(Predicted)
• LogP: 6.70260
• XLogP3: 7.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 362.167065321
• Heavy Atom Count: 28
• Complexity: 460

Purity/Quality:

97% ^*data from raw suppliers

(2-(4-Methoxyphenyl)ethene-1,1,2-triyl)tribenzene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C(=C(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 1-methoxy-4-(1,2,2-triphenylethenyl)Benzene

There total 30 articles about 1-methoxy-4-(1,2,2-triphenylethenyl)Benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C26H21N3 + methoxybenzene (100-66-3) → (2-(4-methoxyphenyl)ethene-1,1,2-triyl)tribenzene (70592-05-1)

Guidance literature:

With trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.201908755

Reference yield: 90.0%

Triphenylvinyl bromide (1607-57-4) + 4-methoxyphenylboronic acid (5720-07-0) → (2-(4-methoxyphenyl)ethene-1,1,2-triyl)tribenzene (70592-05-1)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); Tedicyp; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; for 20h;

DOI:10.1002/ejoc.200390161

Reference yield: 90.0%

para-iodoanisole (696-62-8) + diphenyl acetylene (501-65-5) + phenylboronic acid (98-80-6) → (2-(4-methoxyphenyl)ethene-1,1,2-triyl)tribenzene (70592-05-1)

Guidance literature:

para-iodoanisole; diphenyl acetylene; phenylboronic acid; With potassium hydrogencarbonate; In water; N,N-dimethyl-formamide; at 100 ℃; for 0.166667h;

With bis(benzonitrile)palladium(II) dichloride; In water; N,N-dimethyl-formamide; at 100 ℃; for 24h;

DOI:10.1021/ol034435d

upstream raw materials:

1-(4'-methoxyphenyl)-1,2,2-triphenylethanol

acetyl chloride

1-(4'-methoxyphenyl)-1,2,2-triphenylethane

2-(4-Methoxy-phenyl)-2,3,3-triphenyl-thiirane

Downstream raw materials:

1-(4'-hydroxyphenyl)-1,2,2-triphenylethylene