Ethyl (triethylgermyl)acetate

Base Information

• Chemical Name: Ethyl (triethylgermyl)acetate
• CAS No.: 88011-27-2
• Molecular Formula: C₁₀H₂₂GeO₂
• Molecular Weight: 246.873
• NSC Number: 82087
• DSSTox Substance ID: DTXSID501007903
• Wikidata: Q83004186
• Mol file: 88011-27-2.mol

Synonyms:88011-27-2;Ethyl (triethylgermyl)acetate;NSC82087;DTXSID501007903;NSC-82087

Chemical Property of Ethyl (triethylgermyl)acetate

Chemical Property:

• Vapor Pressure: 0.0303mmHg at 25°C
• Boiling Point: 244.5°Cat760mmHg
• Flash Point: 94.6°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 248.0831577
• Heavy Atom Count: 13
• Complexity: 145

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)C[Ge](CC)(CC)CC

Technology Process of Ethyl (triethylgermyl)acetate

There total 3 articles about Ethyl (triethylgermyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(C2H5)3Ge(SO3CF3) (209072-05-9) + ethyl acetate (141-78-6) → Ethyl-3-triethylgermyl-acetat (88011-27-2)

Guidance literature:

With triethylamine; In diethyl ether; byproducts: Et3NH(triflate); 0°C; distn.; elem. anal.;

DOI:10.1080/00945719809349381

Reference yield: 75.0%

bis(triethylgermyl)mercury (4149-28-4) + ethyl bromoacetate (105-36-2) → Ethyl-3-triethylgermyl-acetat (88011-27-2)

Guidance literature:

In benzene; byproducts: Et3GeBr, Hg; (Et3Ge)2Hg added to a soln. of org. compound, 3.5 h; decanted; solvent removed; fractional distillation;

DOI:10.1007/BF00954376

Reference yield:

→ Ethyl-3-triethylgermyl-acetat (88011-27-2)

Guidance literature:

Diazoessigsaeure-ethylester, Triethylgerman in Anw. von Cu-Pulver;

DOI:10.1016/S0022-328X(00)82221-4

upstream raw materials:

(C₂H₅)3Ge(SO₃CF₃)

ethyl acetate

bis(triethylgermyl)mercury

ethyl bromoacetate