cis-4-Dodecene

Base Information

Chemical Name:cis-4-Dodecene
CAS No.:7206-27-1
Molecular Formula:C₁₂H₂₄
Molecular Weight:168.323
Hs Code.:
DSSTox Substance ID:DTXSID901018097
Nikkaji Number:J97.394G
Mol file:7206-27-1.mol

Synonyms:cis-4-dodecene;(Z)-4-Dodecene;4-Dodecene, (Z)-;(4Z)-4-Dodecene;7206-27-1;PHCKFVVLVZFFLU-CLFYSBASSA-N;DTXSID901018097

Suppliers and Price of cis-4-Dodecene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of cis-4-Dodecene

Chemical Property:

Vapor Pressure:0.255mmHg at 25°C
Melting Point:-38.4°C (estimate)
Refractive Index:1.4262 (estimate)
Boiling Point:207.3°C (estimate)
PSA：0.00000
Density:0.7761 (estimate)
LogP:4.70320
XLogP3:5.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:8
Exact Mass:168.187800766
Heavy Atom Count:12
Complexity:92.2

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCC=CCCC
Isomeric SMILES:CCCCCCC/C=C\CCC

Technology Process of cis-4-Dodecene

There total 3 articles about cis-4-Dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 124-13-0
Octanal

: 1779-51-7
n-butyl(triphenyl)phosphonium bromide

: 7206-27-1
cis-4-dodecene

: 7206-15-7
trans-4-dodecene

Guidance literature:: With potassium carbonate; In 1,4-dioxane; water; for 3h; Product distribution; Heating; various aliphatic and aromatic aldehydes, phosphonium salts; Wittig reaction, catalyzed with K₂CO₃, comparison with NaOH catalysis;

Reference yield:

: 25047-67-0
n-heptyllithium

: 7206-27-1
cis-4-dodecene

Guidance literature:: Multi-step reaction with 2 steps

2: 1.) t-BuLi, 2.) HMPT / 1.) Et₂O, pentane, -78 - (-50) deg C, 15 min, 2.) Et₂O, propane, THF, -50 deg C - room temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; tert.-butyl lithium;
DOI:10.1080/00397919608004635

Reference yield:

: 52886-17-6
(Z)-1-iodo-1-nonene

: 107-08-4
1-iodo-propane

: 7206-27-1
cis-4-dodecene

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; tert.-butyl lithium; Yield given. Multistep reaction; 1.) Et₂O, pentane, -78 - (-50) deg C, 15 min, 2.) Et₂O, propane, THF, -50 deg C - room temperature;
DOI:10.1080/00397919608004635