2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)-

Base Information

• Chemical Name: 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)-
• CAS No.: 23788-22-9
• Molecular Formula: C36H30 N3 O12 P3
• Molecular Weight: 789.568
• Mol file: 23788-22-9.mol

Synonyms:1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexahydro-2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)- (9CI);1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexahydro-2,2,4,4,6,6-hexakis(p-hydroxyphenoxy)- (7CI,8CI);Hexakis(4-hydroxyphenoxy)cyclotriphosphazene

Chemical Property of 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)-

Chemical Property:

• Boiling Point: 908.6°Cat760mmHg
• Flash Point: 503.3°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)-

There total 3 articles about 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2,2,4,4,6,6-hexakis(4-methoxyphenoxy)cyclotriphosphazene (1184-42-5) → 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)cyclotriphosphazatriene (23788-22-9)

Guidance literature:

With boron tribromide; In dichloromethane; at 0 - 20 ℃; for 13h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2018.02.022

Reference yield:

4-Benzyloxyphenol (103-16-2) → 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)cyclotriphosphazatriene (23788-22-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 83 percent / Cs₂CO₃; hexachlorocyclotriphosphazene / acetone / 15 h / Heating

2: 93 percent / Pd(OH)2; cyclohexene / tetrahydrofuran; ethanol / 6 h / Heating

With palladium dihydroxide; 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; caesium carbonate; cyclohexene; In tetrahydrofuran; ethanol; acetone;

DOI:10.1021/ja051042w

Reference yield:

4-methoxy-phenol (150-76-5) → 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)cyclotriphosphazatriene (23788-22-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; sodium hydride / tetrahydrofuran / 36 h / 80 °C / Inert atmosphere

2: boron tribromide / dichloromethane / 13 h / 0 - 20 °C / Inert atmosphere

With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; boron tribromide; sodium hydride; In tetrahydrofuran; dichloromethane;

DOI:10.1016/j.jorganchem.2018.02.022

upstream raw materials:

2,2,4,4,6,6-hexakis(4-methoxyphenoxy)cyclotriphosphazene

4-Benzyloxyphenol

4-methoxy-phenol