[(Dichloroacetyl)oxy](triphenyl)stannane

Base Information

Chemical Name:[(Dichloroacetyl)oxy](triphenyl)stannane
CAS No.:7546-89-6
Molecular Formula:C₂₀H₁₆Cl₂O₂Sn
Molecular Weight:477.962
Hs Code.:
DSSTox Substance ID:DTXSID60587206
Wikidata:Q82479563

Synonyms:7546-89-6;DTXSID60587206;[(Dichloroacetyl)oxy](triphenyl)stannane

Suppliers and Price of [(Dichloroacetyl)oxy](triphenyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of [(Dichloroacetyl)oxy](triphenyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:477.954938
Heavy Atom Count:25
Complexity:380

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)OC(=O)C(Cl)Cl

Technology Process of [(Dichloroacetyl)oxy](triphenyl)stannane

There total 2 articles about [(Dichloroacetyl)oxy](triphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 79-43-6
dichloro-acetic acid

: 124-41-4
sodium methylate

: 639-58-7
triphenyltin chloride

: 7546-89-6
(C₆H₅)3SnOCOCHCl₂

Guidance literature:: In methanol; under dry nitrogen atmosphere; reaction of (C6H5)3SnCl (10 mmol) and CH3ONa(10 mmol) at 0°C; addn. a soln. of CHCl2COOH (10 mmol) in methanol to the formed (C6H5)3SnOCH3 soln.; stirring for 2 h at the same temperature; filtn.; concn. of the solvent under reduced pressure; recrystallization from chloroform;

Reference yield:

: 79-43-6
dichloro-acetic acid

: 17156-69-3
triphenylstannyl(trimethylsilyl)acetylene

: 7546-89-6
triphenylstannyl dichloroacetate

Guidance literature:: In chloroform-d1; byproducts: (CH3)3SiCCH; react. in a NMR-tube at 23°C, addn. of the carboxylic acid soln. to the compd.; detected by NMR; Kinetics;