Benzenemethanol, a-(2Z)-2-butenyl-

Base Information

• Chemical Name: Benzenemethanol, a-(2Z)-2-butenyl-
• CAS No.: 75851-76-2
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol file: 75851-76-2.mol

Synonyms:(Z)-1-Phenyl-pent-3-en-1-ol;(Z)-1-phenylpent-3 -en-1-ol;(Z)-1-phenyl-3-pentene-1-ol;(Z)-1- phenyl-3-penten-1-ol;(Z)-1-phenylpent-3-en-1-ol;Z-5-Hydroxy-5-phenyl-penten-2;Z-1-phenylpent-3-en-1-ol;

Chemical Property of Benzenemethanol, a-(2Z)-2-butenyl-

Chemical Property:

• Boiling Point: 263.3±9.0 °C(Predicted)
• PSA: 20.23000
• Density: 0.991±0.06 g/cm3(Predicted)
• LogP: 2.68620

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenemethanol, a-(2Z)-2-butenyl-

There total 96 articles about Benzenemethanol, a-(2Z)-2-butenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

crotyltributylstannane (31197-41-8,76505-19-6) + benzaldehyde (100-52-7) → (Z)-1-phenyl-3-penten-1-ol (75851-76-2)

Guidance literature:

With dibutyltin chloride; at 25 ℃; for 3h;

DOI:10.1016/S0022-328X(00)81209-7

Reference yield: 94.0%

2,3-dimethylpent-4-en-2-ol (19781-52-3) + benzaldehyde (100-52-7) → 1-phenylpent-3-en-1-ol (75851-76-2,75851-77-3,124004-57-5,141423-28-1,52922-20-0)

Guidance literature:

With tin(II) trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at -25 ℃; for 8h;

DOI:10.1021/ja9810742

Reference yield: 87.0%

(Z)-2-(but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (69611-01-4) + benzaldehyde (100-52-7) → (Z)-1-phenyl-3-penten-1-ol (75851-76-2)

Guidance literature:

With In(OSO₂CF₃)3; In toluene; at 20 ℃; for 0.25h;

DOI:10.1039/b418996e

upstream raw materials:

(E/Z)-crotyl bromide

benzaldehyde

(E)-but-2-enol

2-acetoxy-3-butene

Downstream raw materials:

4-methyl-1-phenyl-hex-5-en-3-ol

(E)-1-phenyl-hept-5-en-3-ol

1-phenylpent-3-en-1-one

1-Phenyl-1-pentanol