[(1S,2S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] 2-morpholin-4-ylacetate

Base Information

Chemical Name:[(1S,2S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] 2-morpholin-4-ylacetate
CAS No.:20314-75-4
Molecular Formula:C16H27NO3
Molecular Weight:281.3905
Hs Code.:
NSC Number:68012
DSSTox Substance ID:DTXSID70942463
Wikidata:Q82919481

Synonyms:20314-75-4;NSC68012;DTXSID70942463;NSC-68012;1,7,7-Trimethylbicyclo[2.2.1]heptan-2-yl (morpholin-4-yl)acetate

Suppliers and Price of [(1S,2S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] 2-morpholin-4-ylacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of [(1S,2S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] 2-morpholin-4-ylacetate

Chemical Property:

Vapor Pressure:3.56E-05mmHg at 25°C
Boiling Point:353.6°Cat760mmHg
Flash Point:167.6°C
Density:1.1g/cm³
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:281.19909372
Heavy Atom Count:20
Complexity:389

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC1(C(C2)OC(=O)CN3CCOCC3)C)C
Isomeric SMILES:C[C@]12CC[C@@H](C1(C)C)C[C@@H]2OC(=O)CN3CCOCC3

Technology Process of [(1S,2S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] 2-morpholin-4-ylacetate

There total 4 articles about [(1S,2S,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] 2-morpholin-4-ylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 110-91-8,99108-56-2
morpholine

: 89299-71-8,4488-59-9
(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 2-chloroacetate

: 20314-75-4
(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 2-morpholinoacetate

Guidance literature:: With triethylamine; at 25 ℃; for 24h;
DOI:10.1039/c6md00657d

Reference yield: 62.0%

: 110-91-8,99108-56-2
morpholine

: 75556-46-6,4488-59-9
(1S,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 2-chloroacetate

: 20314-75-4
(1S,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 2-morpholinoacetate

Guidance literature:: With triethylamine; at 25 ℃; for 24h;
DOI:10.1039/c6md00657d

Reference yield:

: 464-45-9
endo-borneol

: 20314-75-4
(1S,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 2-morpholinoacetate

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine / dichloromethane / 12 h / 15 - 25 °C / Inert atmosphere

2: triethylamine / 24 h / 25 °C

With triethylamine; In dichloromethane;
DOI:10.1039/c6md00657d