tert-butyl phenyl sulfone

Base Information

• Chemical Name: tert-butyl phenyl sulfone
• CAS No.: 4170-72-3
• Molecular Formula: C10H14O2S
• Molecular Weight: 198.286
• Hs Code.: 2904100000
• Mol file: 4170-72-3.mol

Synonyms:tert-butyl-phenyl sulfone;Phenyl t-butyl sulfone;tert.-Butylsulfon-benzol;t-butyl phenyl sulfone;Phenyl tert-butylsulfone;

Chemical Property of tert-butyl phenyl sulfone

Chemical Property:

• Vapor Pressure: 0.000496mmHg at 25°C
• Boiling Point: 323.4°Cat760mmHg
• Flash Point: 171.6°C
• PSA: 42.52000
• Density: 1.096g/cm³
• LogP: 3.33960

Purity/Quality:

95% ^*data from raw suppliers

TERT-BUTYL PHENYL SULFONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tert-butyl phenyl sulfone

There total 22 articles about tert-butyl phenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tert-butyl phenyl sulfide (3019-19-0) → tert-butyl-phenyl sulfone (4170-72-3)

Guidance literature:

With Oxone; In methanol; for 2h; Ambient temperature;

Reference yield: 83.0%

(tert-butylsulfinyl)benzene (62076-10-2,4170-71-2) → tert-butyl-phenyl sulfone (4170-72-3)

Guidance literature:

With thio-xanthene-9-one; oxygen; In pentan-3-one; at 35 - 40 ℃; under 760.051 Torr; Solvent; Schlenk technique; UV-irradiation; Green chemistry;

DOI:10.1016/j.tet.2022.132708

Reference yield: 79.0%

ethyl phenyl sulfone (599-70-2) + methyl iodide (74-88-4) → phenyl isopropyl sulfone (4238-09-9) + tert-butyl-phenyl sulfone (4170-72-3)

Guidance literature:

ethyl phenyl sulfone; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1002/ejoc.201301553

upstream raw materials:

tert-butyl phenyl sulfide

phenyl isopropyl sulfone

methyl iodide

t-butyl phenylazo sulfone

Downstream raw materials:

2-Butyl-α,α,α',α'-tetraphenyl-m-benzoldimethanol

2-n-butylisophthalic acid

2-methyl-1,3-benzenedicarbocylic acid

2-Butyl-α,α'-diphenyl-m-benzoldimethanol

Refernces

• 1、 Li, Xiaotong,Wang, Yu,Xie, Xiaomin,Yang, Liqun,Zhang, Zhaoguo. "Visible-light-promoted aerobic oxidation of sulfides and sulfoxides in ketone solvents". . . Retrieved 2022/03/09.
• 2、 Mangaonkar, Saeesh R.,Kole, Priyanka B.,Singh, Fateh V.. "Oxidation of Organosulfides to Organosulfones with Trifluoromethyl 3-Oxo-1λ 3,2-benziodoxole-1(3 H)-carboxylate as an Oxidant". supporting information. p. 199 - 202. Retrieved 2017/09/28.